The grafted carbendazim and 2,4,6-tris(dimethylaminomethyl)phenyl group onto polyurethane to improve its antifungal effectiveness and hydrophilicity

被引：2

作者：

Chung, Yong-Chan ^{[1
]}

Park, Ji Eun ^{[2
]}

Choi, Jae Won ^{[2
]}

Chun, Byoung Chul ^{[2
]}

机构：

[1] Univ Suwon, Dept Chem, Hwaseong 18323, South Korea

[2] Inje Univ, Sch Nano Engn, Gimhae 50834, South Korea

来源：

POLYMER BULLETIN | 2021年 / 78卷 / 02期

基金：

新加坡国家研究基金会;

关键词：

Carbendazim; Hydrophilicity; Antifungal; Polyurethane; EXPANDED POLY(TETRAFLUOROETHYLENE); TERMINATED POLYBUTADIENE; WATER COMPATIBILITY; SHAPE RECOVERY; POLYMERS; ANTIBACTERIAL; SURFACES; SAMPLES; IMPACT; POLYMERIZATION;

D O I：

10.1007/s00289-020-03126-2

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The antifungal agent carbendazim and the water-compatible functional group 2,4,6-tris(dimethylaminomethyl)phenol (TDMP) were jointly grafted to polyurethane (PU) to develop a water-compatible antifungal PU. The water compatibility of the PU surface improved strikingly after the protonation of TDMP, as confirmed by water contact angle tests. The combined grafting of carbendazim and TDMP affected the melting and glass transition of soft segments and sharply increased the tensile stress and shape recovery capability. Carbendazim was selected as a grafted antifungal functional group due to its wide effective range of antifungal activity and its large production volume. PUs with grafted carbendazim and TDMP completely suppressed the growth of a mixture of fungi, unlike ordinary PU. Therefore, the joint grafting of both carbendazim and TDMP led to improved water compatibility, breaking tensile stress, shape recovery capability, and antifungal activity.

引用

页码：621 / 642

页数：22

共 50 条

[1] The grafted carbendazim and 2,4,6-tris(dimethylaminomethyl)phenyl group onto polyurethane to improve its antifungal effectiveness and hydrophilicity
Yong-Chan Chung
Ji Eun Park
Jae Won Choi
Byoung Chul Chun
Polymer Bulletin, 2021, 78 : 621 - 642
[2] Hydrophilic Modification of a Polyurethane Surface Using Grafted 2,4,6-Tris(dimethylaminomethyl) Phenol
Yong-Chan Chung
Ji Young Kim
Ji Eun Park
Byoung Chul Chun
Fibers and Polymers, 2021, 22 : 904 - 915
[3] Hydrophilic Modification of a Polyurethane Surface Using Grafted 2,4,6-Tris(dimethylaminomethyl) Phenol
Chung, Yong-Chan
Kim, Ji Young
Park, Ji Eun
Chun, Byoung Chul
FIBERS AND POLYMERS, 2021, 22 (04) : 904 - 915
[4] Contact allergy to 2,4,6-tris(dimethylaminomethyl)phenol
Brooke, R
Beck, MH
CONTACT DERMATITIS, 1998, 38 (05) : 284 - 285
[5] Phenyl[2,4,6-tris(1-methylethyl)phenyl]methanethione and 4-methoxyphenyl[2,4,6-tris(1-methylethyl)phenyl]methathione
Univ of British Columbia, Vancouver, Canada
Acta Crystallogr Sect C Cryst Struct Commun, Pt 9 (1257-1259):
[6] Phenyl[2,4,6-tris(1-methylethyl)phenyl]methanethione and 4-methoxyphenyl[2,4,6-tris(1-methylethyl)phenyl]methanethione
Fu, TY
Scheffer, JR
Trotter, J
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 1257 - 1259
[7] (HEXAKIS[2,4,6-TRIS(TRIFLUOROMETHYL)PHENYL]-CYCLOTRISTANNOXANE)2
URIA, JFV
BELAY, M
EDELMANN, FT
SHELDRICK, GM
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 403 - 407
[8] SYNTHESIS OF DIMETHACRYLATE EPOXIDE OLIGOMERS IN THE PRESENCE OF 2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL
KOVALENKO, OV
BELOGORODSKAYA, KV
LYUTKEVICH, GV
AVDONINA, ED
JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1988, 61 (11): : 2285 - 2287
[9] 2,4,6-Tris(dimethylaminomethyl)phenol: The allergen which came in from the cold
Geier, Johannes
Dickel, Heinrich
Schroder-Kraft, Claudia
Gina, Michal
Simon, Dagmar
Weisshaar, Elke
Lang, Claudia
Brans, Richard
Bauer, Andrea
Loeffler, Harald
Schubert, Steffen
CONTACT DERMATITIS, 2023, 88 (04) : 316 - 318
[10] 2,4,6-TRIS(TRIFLUOROMETHYL)PHENYL AND 2,4,6-TRIS(TRIFLUOROMETHYL)DITHIOBENZOATE AS LIGANDS IN COBALT(II) AND NICKEL(II) COMPOUNDS
BELAY, M
EDELMANN, FT
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 479 (1-2) : C21 - C24

← 1 2 3 4 5 →