Hierarchical MoSe2 Nanosheets/Reduced Graphene Oxide Composites as Anodes for Lithium-Ion and Sodium-Ion Batteries with Enhanced Electrochemical Performance

被引:122
|
作者
Zhang, Zhian [1 ]
Fu, Yun [1 ]
Yang, Xing [1 ]
Qu, Yaohui [1 ]
Zhang, Zhiyong [1 ]
机构
[1] Cent S Univ, Sch Met & Environm, Changsha 410083, Hunan, Peoples R China
来源
CHEMNANOMAT | 2015年 / 1卷 / 06期
关键词
graphene; hierarchical structures; lithium-ion batteries; MoSe2; sodium-ion batteries; TRANSITION-METAL DICHALCOGENIDES; HIGH-CAPACITY; MOLYBDENUM-DISULFIDE; ELECTRODE MATERIALS; ENERGY-CONVERSION; CARBON NANOFIBERS; RATE CAPABILITY; STORAGE; NANOCOMPOSITES; MICROSPHERES;
D O I
10.1002/cnma.201500097
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The preparation and electrochemical storage behavior of hierarchical MoSe2/reduced graphene oxide (rGO) composites were studied. The preparation was achieved by a facile hydrothermal route. The results show that MoSe2 has a high capacity for lithium ion and sodium ion storage and that the incorporation of rGO has further improved the electrochemical property of MoSe2 effectively. As anode materials for lithium-ion and sodium-ion batteries, the MoSe2/rGO composites demonstrate excellent rate performance and cycling stability of 917 mA h g(-1) after 100 cycles for Li+ storage and 430 mA h g(-1) after 200 cycles for Na+ storage at a current density of 0.5 Ag-1, which is attributed to the robust hierarchical structure and the synergistic effects between MoSe2 nano-sheets and rGO. Therefore, the electrochemical evaluations suggest that the obtained hierarchical structure MoSe2/rGO composites hold great potential as anode materials for lithium-ion and sodium-ion batteries.
引用
收藏
页码:409 / 414
页数:6
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