Chiral Buckybowl Molecules

被引：25
|
作者：
Kanagaraj, Kuppusamy [1 ]
Lin, Kangjie [1 ]
Wu, Wanhua [1 ]
Gao, Guowei [1 ]
Zhong, Zhihui [2 ]
Su, Dan
Yang, Cheng [1 ]
机构：
[1] Sichuan Univ, Coll Chem, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China
[2] Sichuan Univ, West China Med Ctr, State Key Lab Biotherapy, Chengdu 610064, Peoples R China
来源：
SYMMETRY-BASEL | 2017年 / 9卷 / 09期
基金：
中国国家自然科学基金;
关键词：
buckybowl; corannulene; sumanene; bowl chirality; bowl inversion; asymmetric synthesis; chiral resolution; TO-BOWL INVERSION; REGIOSELECTIVE CYCLOTRIMERIZATION; CORANNULENE DERIVATIVES; CARBON NANOTUBE; SUMANENE; METAL; COORDINATION; HYDROCARBON; CHEMISTRY; SURFACE;
D O I：
10.3390/sym9090174
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Buckybowls are polynuclear aromatic hydrocarbons that have a curved aromatic surface and are considered fragments of buckminsterfullerenes. The curved aromatic surface led to the loss of planar symmetry of the normal aromatic plane and may cause unique inherent chirality, so-called bowl chirality, which it is possible to thermally racemize through a bowl-to-bowl inversion process. In this short review, we summarize the studies concerning the special field of bowl chirality, focusing on recent practical aspects of attaining diastereo/enantioenriched chiral buckybowls through asymmetric synthesis, chiral optical resolution, selective chiral metal complexation, and chiral assembly formation.
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页数：25
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