Syntheses, crystal structures and fluorescent properties of three coordination polymers assembled from flexible bis-(imidazole-4,5-dicarboxylate) ligand and d10/s2 metal ions

被引：9
|
作者：
Yuan, Gang [1 ]
Zhang, Chao [1 ]
Shao, Kui-Zhan [2 ]
Zhou, Wan-Li [1 ]
Wei, Xuan [1 ]
Wang, Feng-Chun [1 ]
Su, Zhong-Min [2 ]
机构：
[1] Tonghua Normal Univ, Fac Chem, Tonghua 134002, Peoples R China
[2] Northeast Normal Univ, Fac Chem, Inst Funct Mat Chem, Changchun 130024, Jilin, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2019年 / 100卷
关键词：
Imidazole-4,5-dicarboxylic acid; d(10) metal; Pb-II complex; Fluorescence; MBB; Topology; AGGREGATION-INDUCED EMISSION; ORGANIC FRAMEWORKS; ACID SYNTHESIS; SERIES; NANOPARTICLES; COMPLEXES; PHOTOLUMINESCENCE; LUMINESCENCE; ADSORPTION; DIVERSITY;
D O I：
10.1016/j.inoche.2018.12.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new coordination polymers, [Zn(H2L2)(H2O)](n) (1), [Cd(H2L2)(H2O)](n) (2) and {[Pb(H2L2)](n) (3) (H4L = 1,1'-(propane-1,3-diyl)bis(1H-imidazole-4,5-dicarboxylic acid)) have been successfully prepared under hydrothermal conditions. Complexes 1 and 2 are isomorphic and exhibit 2D fes network constructed from interconnected ring-like [M-2(H2L)(2)] (M = Zn or Cd) MBBs. Complex 3 displays a 3D covalent framework with seh-3,5-P2(1)/c net topology built by interconnected ring-like [Pb-4(H2L)(2)] MBBs. Moreover, the thermal stability and fluorescent properties of these complexes were investigated in detail.
引用
收藏
页码：16 / 20
页数：5
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