Control of the nanoscale crystallinity and phase separation in polymer solar cells

被引：166

作者：

Chu, Chih-Wei ^{[1
]}

Yang, Hoichang ^{[3
]}

Hou, Wei-Jen ^{[1
]}

Huang, Jinsong ^{[1
]}

Li, Gang ^{[1
,2
]}

Yang, Yang ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Mat Sci & Engn, Los Angeles, CA 90095 USA

[2] Solarmer Energy Inc, El Monte, CA 91731 USA

[3] Rensselaer Polytech Inst, Rensellaer Nanotechnol Ctr, Troy, NY 12180 USA

来源：

APPLIED PHYSICS LETTERS | 2008年 / 92卷 / 10期

关键词：

D O I：

10.1063/1.2891884

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Grazing-incidence x-ray diffraction and atomic force microscopy were performed on bulk heterojunction regioregular poly(3-hexylthiophene) (RR-P3HT) [6,6]-phenyl-C-71-butyric acid methyl esters spin-cast films with different film processing conditions to correlate the crystalline nanostructure of P3HT with the corresponding solar cell performance. The increase in long wavelength absorption for solvent annealed films is related to highly conjugated crystal structure of RR-P3HT phase-separated in the active layer. Upon thermal annealing, the solvent annealed 50-nm-thick device shows high solar cell performance with fill factor up to 73% and power conversion efficiency of 3.80%. (c) 2008 American Institute of Physics.

引用

页数：3

共 50 条

[1] Improving the performance of polymer solar cells by adjusting the crystallinity and nanoscale phase separation
陈卫兵
许宗祥
李凯
徐先贤
Roy V. A. L.
黎沛涛
支志明
[J]. Chinese Physics B, 2012, 21 (07) : 585 - 590
[2] Improving the performance of polymer solar cells by adjusting the crystallinity and nanoscale phase separation
Chen, Wei-Bing
Xu, Zong-Xiang
Li, Kai
Chui, Stephen Sin-Yin
Roy, V. A. L.
Lai, Pui-To
Che, Chi-Ming
[J]. CHINESE PHYSICS B, 2012, 21 (07)
[3] Effect of solvent mixture on the nanoscale phase separation in polymer solar cells
Yao, Yan
Hou, Jianhui
Xu, Zheng
Li, Gang
Yang, Yang
[J]. ADVANCED FUNCTIONAL MATERIALS, 2008, 18 (12) : 1783 - 1789
[4] Nanoscale phase separation control in rationally designed conjugated polymer solar cells processed using co-additives
Bao, Xichang
Sun, Liang
Gu, Chuantao
Du, Zhengkun
Wen, Shuguang
Wang, Ting
Wang, Ning
Yang, Renqiang
[J]. RSC ADVANCES, 2015, 5 (21) : 16234 - 16238
[5] Morphology Control at the Nanoscale of Polymer Composites for Organic Solar Cells
Ratier, Bernard
Boucle, Johann
Boloma, Ghislain
Rossignol, Fabrice
Coudert, Valerie
[J]. ADVANCES IN NANODEVICES AND NANOFABRICATION, 2012, : 99 - 115
[6] Influence of Crystallinity and Energetics on Charge Separation in Polymer–Inorganic Nanocomposite Films for Solar Cells
Neha Bansal
Luke X. Reynolds
Andrew MacLachlan
Thierry Lutz
Raja Shahid Ashraf
Weimin Zhang
Christian B. Nielsen
Iain McCulloch
Dylan G. Rebois
Thomas Kirchartz
Michael S. Hill
Kieran C. Molloy
Jenny Nelson
Saif A. Haque
[J]. Scientific Reports, 3
[7] Phase-separation Mechanism and Morphological Control in All-polymer Solar Cells
Song, Chun-peng
Qu, Yi
Liu, Jian-gang
Han, Yan-chun
[J]. ACTA POLYMERICA SINICA, 2018, (02): : 145 - 163
[8] Phase separation, crystallinity and monomer-aggregate population control in solution processed small molecule solar cells
Zheng, Chenyu
Bleier, Dylan
Jalan, Ishita
Pristash, Sarah
Penmetcha, Anirudh Raju
Hestand, Nicholas J.
Spano, Frank C.
Pierce, Michael S.
Cody, Jeremy A.
Collison, Christopher J.
[J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2016, 157 : 366 - 376
[9] Efficient Ternary Polymer Solar Cells with Tunable Crystallinity and Phase Separation of Active Layers via Incorporating GHK-Cu
Huang, Jinzhen
Yu, Huangzhong
[J]. ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (39) : 46927 - 46937
[10] Improved phase separation in polymer solar cells by solvent blending
Kaestner, Christian
Muhsin, Burhan
Wild, Andreas
Egbe, Daniel A. M.
Rathgeber, Silke
Hoppe, Harald
[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2013, 51 (11) : 868 - 874

← 1 2 3 4 5 →