Preparation of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane from 2,6,8,12-tetraacetyl 2,4,6,8,12-hexaazaisowurtzitane using Various Nitrating Agents

被引：0

作者：

Bayat, Yadollah ^{[1
]}

Mokhtari, Javad ^{[2
]}

机构：

[1] Malek Ashtar Univ Technol, Fac Mat & Mfg Technol, Tehran, Iran

[2] Tarbiat Modares Univ, Tehran, Iran

来源：

DEFENCE SCIENCE JOURNAL | 2011年 / 61卷 / 02期

关键词：

CL-20; nitration; HNIW; TAIW; synthesis of explosives; propellant compounds; CL-20; HYDROLYSIS; KINETICS;

D O I：

10.14429/dsj.61.606

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (HNIW), a high energy material with cage structure, is considered as the most powerful explosive today. It is usually prepared via nitration with concentrated nitric and sulphuric acid, but this technique pollutes the environment. In this study, HNIW was synthesised by nitration of 2,6,8,12-tetraacetyl 2,4,6,8,12-hexaazaisowurtzitane (TAIW) various nitrating agents. Using this nitrating agent, the reaction eliminated use of concentrated sulphuric acid and was also environmental- friendly. Meanwhile, the effects of reaction temperature, time, and other factors on yield were studied. The structure of the compound was characterised by elemental analysis, Infrared, (1)HNMR and MS.

引用

页码：171 / 173

页数：3

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