Silver-Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions

被引：25

作者：

Li, Man-Bo ^{[1
,2
]}

Yang, Ying ^{[1
]}

Rafi, Abdolrahim A. ^{[3
]}

Oschmann, Michael ^{[2
]}

Grape, Erik Svensson ^{[4
]}

Inge, A. Ken ^{[4
]}

Cordova, Armando ^{[3
]}

Backvall, Jan-E ^{[2
,3
]}

机构：

[1] Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Anhui, Peoples R China

[2] Stockholm Univ, Arrhenius Lab, Dept Organ Chem, S-10691 Stockholm, Sweden

[3] Mid Sweden Univ, Dept Nat Sci, Holmgatan 10, S-85179 Sundsvall, Sweden

[4] Stockholm Univ, Arrhenius Lab, Dept Mat & Enviromental Chem, S-10691 Stockholm, Sweden

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2020年 / 59卷 / 26期

基金：

瑞典研究理事会;

关键词：

carbonylation; heterogeneous catalysis; palladium; polycyclic compound; silver; CARBOCYCLIZATION-CARBONYLATION; GAMMA-LACTAMS; CASCADE REACTION; ALLENES; CONSTRUCTION; HETEROCYCLES; LIGAND;

D O I：

10.1002/anie.202001809

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A silver-triggered heterogeneous Pd-catalyzed oxidative carbonylation has been developed. This heterogeneous process exhibits high efficiency and good recyclability, and was utilized for the one-pot construction of polycyclic compounds with multiple chiral centers. AgOTf was used to remove chloride ions in the heterogeneous catalyst Pd-AmP-CNC, thereby generating highly active Pd-II, which results in high efficiency of the heterogeneous catalytic system.

引用

页码：10391 / 10395

页数：5

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