Synthesis, Crystal Structure and Magnetic Property of a One-Dimensional Samarium(III) Coordination Polymer

被引：3

作者：

Lin, Shuang-Yan ^{[1
,2
]}

Zhao, Lang ^{[2
]}

Xu, Gong-Feng ^{[2
]}

Guo, Yun-Nan ^{[2
]}

Liu, Gui-Xia ^{[1
]}

Tang, Jinkui ^{[2
]}

机构：

[1] Changchun Univ Sci & Technol, Sch Chem & Environm Engn, Changchun 130022, Peoples R China

[2] Chinese Acad Sci, State Key Lab Rare Earth Resource Utilizat, Changchun Inst Appl Chem, Changchun 130022, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2011年 / 41卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Samarium(III) coordination polymer; Crystal structure; Magnetic property; LUMINESCENT PROPERTIES; LANTHANIDE COMPLEXES; LIGAND; IONS;

D O I：

10.1007/s10870-010-9842-3

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A novel samarium(III) polymer, [Sm-2(C6H5COO)(6)(CH3OH)(3)]center dot CH3OH (1) has been synthesized and characterized by single crystal X-ray diffraction and magnetic measurements. Polymer 1 crystallizes in monoclinic space group P2(1)/c, with a = 15.1247(6), b = 18.3351(7), c = 21.1266(6) , beta = 126.830(2)A degrees, V = 4689.4(3) (3), and Z = 4. Single crystal X-ray analysis reveals a chain-like structure of 1 consisted of alternating eight- and nine-coordinate Sm(III) ions bridged by benzoate ligands in different coordination modes. A treatment of the variable-temperature magnetic susceptibility using an expression deduced from free-ion approximation and molecular field theory suggests the existence of a weak antiferromagnetic coupling between the samarium ions.

引用

页码：77 / 81

页数：5

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