Use of Extractants in the Synthesis of Calcium Silicates and Calcium Silicate-Based Materials

被引:2
|
作者
Akat'eva, L. V. [1 ]
Gladun, V. D. [2 ]
Khol'kin, A. I. [1 ]
机构
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
[2] Moscow State Tech Univ Stankin, Egorev Technol Inst Dept, Moscow 127994, Russia
关键词
phosphogypsum; silica gel; hydrothermal synthesis; xonotlite; wollastonite; fine powders; solid extractants; tetraalkylammonium di(2-ethylhexyl)dithiophosphate; sorption properties; binary dyes; organomineral paints; extraction-pyrolitic method; shell ceramic paints;
D O I
10.1134/S0040579511050010
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
During hydrothermal synthesis of calcium hydrosilicates from phosphogypsum and silica gel, the addition of quaternary ammonium bases during the crystallization step makes it possible to decrease the particle size and preserve the high disparity of calcium silicate product (wollastonite) after high-temperature annealing (from 900 to 1200 degrees C). Solid extractants (TVEKS) based on xonotlite and wollastonite were obtained and tested with the use of a binary extractant, namely, methyltrioctylammonium di(2-ethylhexyl) dithiophosphate. The methods of preparation of organomineral paints based on calcium hydrosilicate were designed with the use of binary dyes of various compositions. Shell ceramic cobalt paints on a wollastonite carrier were obtained with the use of extraction-pyrolitic method.
引用
收藏
页码:702 / 712
页数:11
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