A titanium-based metal-organic framework as an ultralong cycle-life anode for PIBs

被引：93
|
作者：
An, Yongling [1 ]
Fei, Huifang [1 ]
Zhang, Zhen [1 ]
Ci, Lijie [1 ]
Xiong, Shenglin [2 ]
Feng, Jinkui [1 ]
机构：
[1] Shandong Univ, K SDU & Rice Joint Ctr Carbon Nanomat, Key Lab Liquid Solid Struct Evolut & Proc Mat, Minist Educ,Sch Mat Sci & Engn, Jinan 250061, Shandong, Peoples R China
[2] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Shandong, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 59期
基金：
中国国家自然科学基金;
关键词：
POTASSIUM-ION BATTERIES; NITROGEN-DOPED CARBON; ENERGY-STORAGE; SODIUM; PERFORMANCE; INTERCALATION; ELECTRODES; DICARBOXYLATE; TEREPHTHALATE; NA2C8H4O4;
D O I：
10.1039/c7cc03606j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We achieved excellent anode performance for PIBs based on a metal-organic framework MIL-125(Ti) for the first time. It can deliver a capacity of 208 mA h g(-1) at a rate of 10 mA g(-1) and a high capacity retention of 90.2% after 2000 cycles at a high rate of 200 mA g(-1) with a high coulombic efficiency. The K+ storage mechanism is investigated by the ex situ XRD and IR techniques and confirms that potassium ions are reversibly inserted into the organic moiety without direct engagement of Ti ions.
引用
收藏
页码：8360 / 8363
页数：4
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