A comprehensive review on oxygen transport membranes: Development history, current status, and future directions

被引:36
|
作者
Bai, Wei [1 ]
Feng, Junxiao [1 ]
Luo, Chunhuan [1 ]
Zhang, Panpan [2 ]
Wang, Hailiang [3 ]
Yang, Yanru [2 ]
Zhao, Yujie [1 ]
Fan, Huanbao [1 ]
机构
[1] Univ Sci Technol Beijing, Sch Energy & Environm Engn, Beijing 100083, Peoples R China
[2] China Univ Min & Technol Beijing, Res Ctr Solid Oxide Fuel Cell, Beijing 100083, Peoples R China
[3] Xinxing Cathay Int Grp, Cent Res Inst, Technol Ctr, Beijing 100070, Peoples R China
关键词
Mixed ionic-electronic conduction; Oxygen transport membranes; Dual-phase membrane; Perovskite; Fluorite; HOLLOW-FIBER MEMBRANE; DUAL-PHASE MEMBRANE; CERIA-BASED ELECTROLYTES; RATE-DETERMINING STEP; OXIDE FUEL-CELLS; FLUORITE-TYPE CE0.8PR0.2O2-DELTA; ENHANCED IONIC-CONDUCTIVITY; CATALYTIC PARTIAL OXIDATION; CERAMIC-BASED MEMBRANES; FLUIDIZED-BED REACTOR;
D O I
10.1016/j.ijhydene.2021.08.177
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In view of its important role as raw materials in various energy and environment fields, pure oxygen has been widely required. The present cryogenic distillation, polymeric membrane and pressure swing adsorption (PSA) air separation methods are either energy intensive or producing non-high purity oxygen. The comparative analysis of the inorganic dense ceramic-based oxygen transport membranes (OTMs) with these traditional oxygen production technologies and the H-2/O-2 production by electrolysis of water shows irreplaceable advantages. The oxygen transport mechanism has been elaborated further to reveal the theoretical basis for the development of OTMs. The dual-phase membranes that have been widely studied are divided into three types according to the conduction paths of oxygen ions and electrons. Based on a review of the different types of OTM materials experienced in the past 30 years, its applications such as oxygen-enriched combustion involving H-2 and membrane reactors have been discussed. Finally, challenges and future directions are analyzed according to potential industrial design directions and competitive technologies of OTMs. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:36257 / 36290
页数:34
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