Novel environmentally sustainable cardanol-based plasticizer covalently bound to PVC via click chemistry: synthesis and properties

被引：64
|
作者：
Yang, Po [1 ,2 ]
Yan, Jun [1 ]
Sun, Huazhen [1 ]
Fan, Haojun [1 ]
Chen, Yi [1 ]
Wang, Fang [1 ]
Shi, Bi [1 ]
机构：
[1] Sichuan Univ, Natl Engn Lab Clean Technol Leather Manufacture, Chengdu 610065, Peoples R China
[2] Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat Engn, Chengdu 610065, Peoples R China
来源：
RSC ADVANCES | 2015年 / 5卷 / 22期
基金：
中国博士后科学基金;
关键词：
BLOOD-STORAGE BAG; POLY(VINYL CHLORIDE); DI(2-ETHYLHEXYL) PHTHALATE; HAZARDOUS PLASTICIZER; SURFACE MODIFICATION; ESTER THIOLS; MIGRATION; RAT; PERFORMANCE; CHALLENGES;
D O I：
10.1039/c4ra15527k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An approach covalently linking cardanol, a well-known renewable organic resource of the cashew industry, to PVC chains using the click reaction has been studied. Under the conditions, cardanol was covalently linked to PVC chains as a natural internal plasticizer. The modified PVC exhibited decreased glass transition temperature, excellent thermal stability and near-zero migration. We believe this approach may help researchers design and explore novel environmentally sustainable plasticizers and apply them in harsh conditions.
引用
收藏
页码：16980 / 16985
页数：6
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