Titanium(IV) complexes of trianionic amine triphenolate ligands

被引：92
|
作者：
Kol, M [1 ]
Shamis, M
Goldberg, I
Goldschmidt, Z
Alfi, S
Hayut-Salant, E
机构：
[1] Tel Aviv Univ, Raymond & Beverly Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel
[2] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel
[3] Coll Judea & Samaria, IL-44837 Ariel, Israel
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 04期
基金：
以色列科学基金会;
关键词：
phenolate ligands; tripodal ligands; titanium complexes; X-ray structure;
D O I：
10.1016/S1387-7003(01)00157-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two trianionic amine triphenolate ligands are introduced and their isopropoxide Ti(IV) complexes synthesized. The two complexes are mononuclear and C-3-symmetrical on the NMR timescale. High barriers to inversion (DeltaG double dagger > 65 KJ mol(-1)) between the enantiomers of each complex were found. The complex derived from the bulkier tripodal ligand shows a better resistance to hydrolysis. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：177 / 179
页数：3
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