Asymmetric synthesis. Part 29: Asymmetric hydroformylation of styrene catalyzed by chiral spiro diphosphite-rhodium(I) complexes

被引：54
|
作者：
Jiang, YZ [1 ]
Xue, S
Li, Z
Deng, JG
Mi, AQ
Chan, ASC
机构：
[1] Acad Sinica, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
[2] Hong Kong Polytech Univ, Hong Kong, Peoples R China
来源：
TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 18期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1016/S0957-4166(98)00339-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Chiral diphosphite ligands L-1-L-3 were prepared by the reaction of (1S,5S,6R)-(cis,trans)-spiro[4.4]nonane-1,6-diol with chlorophosphites. These ligands were tested in the rhodium catalyzed hydroformylation of styrene and enantioselectivities up to 69% were achieved. High regioselectivities (97%) to 2-phenylpropanal and high yields (98%) were obtained under mild reaction conditions. The influence of reaction conditions is also discussed. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：3185 / 3189
页数：5
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