An efficient, catalytic, aerobic, oxidative iodination of arenes using the H5PV2Mo10O40 polyoxometalate as catalyst

被引:81
|
作者
Branytska, OV [1 ]
Neumann, R [1 ]
机构
[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel
来源
JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 24期
关键词
D O I
10.1021/jo035271h
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Iodination of arenes was carried out by reacting 1 equiv of arene substrate with 0.5 equiv of iodine under an oxygen atmosphere with H5PV2Mo10O40 as oxidation catalyst. The synthesis is an inherently waste-free method for the preparation of iodoarenes.
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页码:9510 / 9512
页数:3
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