Alkylation of dianions derived from 2-(1-iminoalkyl) phenols: Synthesis of functionalized 2-acyl phenols.

被引：26
|
作者：
Cimarelli, C [1 ]
Palmieri, G [1 ]
机构：
[1] Univ Camerino, Dipartimento Sci Chim, I-62032 Camerino, Italy
来源：
TETRAHEDRON | 1998年 / 54卷 / 51期
关键词：
alkylation; imines; phenols; lithium and compounds;
D O I：
10.1016/S0040-4020(98)00985-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A method has been developed for the almost exclusive C-alkylation of the 2-(1-iminoalkyl) phenols 1, important organic compounds with a range of employment, which allows the preparation of complex derivatives 4 with good yields starting from easily available materials. The operational simplicity of this method take advantages in providing a variety of alkylated 2-acyl phenols 5 by an easy hydrolysis of the 2-(1-iminoalkyl) phenols 4. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：15711 / 15720
页数：10
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