Physicochemical properties of palladium adsorbents as catalysts in liquid-phase hydrogenation

被引:3
|
作者
Efremov, E. V. [1 ]
Filippov, D. V. [1 ]
Barbov, A. V. [1 ]
机构
[1] Ivanovo State Univ Chem & Technol, Pr Sheremetevskiy 7, Ivanovo 153000, Russia
关键词
19;
D O I
10.1134/S2070205116030072
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The structure and physicochemical properties of palladium catalysts used in liquid-phase hydrogenation processes were studied with the use of adsorption, calorimetric, thermogravimetry, and temperature-programmed reduction techniques. The specific surface areas and average sizes and volume of pores of the adsorbents were determined. The palladium on activated carbon catalysts was found to possess a complex porous structure, whereas palladium on combined alumina and coal carrier catalysts is an adsorbent with a nonporous structure. The concentration of the applied metal and the nature of a support have a significant impact on the physicochemical properties of palladium catalysts.
引用
收藏
页码:425 / 430
页数:6
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