Formic Acid-Based Liquid Organic Hydrogen Carrier System with Heterogeneous Catalysts

被引：162

作者：

Zhong, Heng ^{[1
]}

Iguchi, Masayuki ^{[1
]}

Chatterjee, Maya ^{[1
]}

Himeda, Yuichiro ^{[2
]}

Xu, Qiang ^{[3
]}

Kawanami, Hajime ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Res Inst Chem Proc Technol, Miyagino Ku, 4-2-1 Nigatake, Sendai, Miyagi 9838551, Japan

[2] Natl Inst Adv Ind Sci & Technol, Res Inst Energy Frontier, 1-1-1 Higashi, Tsukuba, Ibaraki 3058565, Japan

[3] Kyoto Univ, Natl Inst Adv Ind Sci & Technol, Chem Energy Mat Open Innovat Lab ChEM OIL, AIST,Sakyo Ku, Kyoto 606 6068501, Japan

来源：

ADVANCED SUSTAINABLE SYSTEMS | 2018年 / 2卷 / 02期

基金：

日本科学技术振兴机构;

关键词：

carbon dioxide; formic acid; heterogeneous catalysts; hydrogen; liquid organic hydrogen carriers; REDUCED GRAPHENE OXIDE; ROOM-TEMPERATURE DEHYDROGENATION; CO-FREE HYDROGEN; EFFICIENT CATALYST; PALLADIUM NANOPARTICLES; HIGH-PERFORMANCE; FACILE SYNTHESIS; CARBON NANOSPHERES; PD NANOPARTICLES; STORAGE MATERIAL;

D O I：

10.1002/adsu.201700161

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Formic acid (HCOOH), with a hydrogen capacity of 4.3 wt%, has attracted increasing interest in the utilization as a promising H-2 carrier. The CO2HCOOH cycle is believed to be a simple and environmental friendly process for the charge and discharge of H-2. In this review, the state-of-the-art technologies and recent results of the heterogeneously catalyzed dehydrogenation of formic acid are summarized. Based on these achievements, future outlooks for improving this system for practical applications are proposed.

引用

页数：17

共 50 条

[1] Application of Heterogeneous Catalysis in Formic Acid-Based Hydrogen Cycle System
Wang, Zhenzhen
Qian, Junfeng
Sun, Zhonghua
Zhang, Zhihui
He, Mingyang
Chen, Qun
[J]. CATALYSTS, 2023, 13 (08)
[2] Review on heterogeneous catalysts for hydrogen generation via liquid-phase formic acid decomposition
Wang, Tong
Xue, Wei
Wang, Yan-Ji
[J]. Gao Xiao Hua Xue Gong Cheng Xue Bao/Journal of Chemical Engineering of Chinese Universities, 2019, 33 (01): : 1 - 9
[3] Dehydrogenation of Formic Acid by Heterogeneous Catalysts
Li, Jun
Zhu, Qi-Long
Xu, Qiang
[J]. CHIMIA, 2015, 69 (06) : 348 - 352
[4] Process intensification for generating and decomposing formic acid, a liquid hydrogen carrier
Egbert, Jonathan D.
Grubel, Katarzyna
Howe, Daniel T.
Weber, Robert S.
Agarwal, Arun S.
Brix, Todd
[J]. IET RENEWABLE POWER GENERATION, 2022, 16 (14) : 2957 - 2963
[5] Nano-catalysts for the synthesis/dehydrogenation of formic acid as a renewable hydrogen carrier
Mori, Kohsuke
Masuda, Shinya
Yamashita, Hiromi
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
[6] Formic Acid as a Hydrogen Energy Carrier
Eppinger, Jorg
Huang, Kuo-Wei
[J]. ACS ENERGY LETTERS, 2017, 2 (01): : 188 - 195
[7] Pd Catalyzed, Acid Accelerated, Rechargeable, Liquid Organic Hydrogen Carrier System Based on Methylpyridines/Methylpiperidines
Xie, Yinjun
Milstein, David
[J]. ACS APPLIED ENERGY MATERIALS, 2019, 2 (06): : 4302 - 4308
[8] An ursodeoxycholic acid-based targetable DNA carrier system
Walton, CM
Barrows, GH
Wu, CH
Wu, GY
[J]. HEPATOLOGY, 1998, 28 (04) : 504A - 504A
[9] Computational Studies on Microreactors for the Decomposition of Formic Acid for Hydrogen Production Using Heterogeneous Catalysts
Harkou, Eleana
Adamou, Panayiota
Georgiou, Kyproula
Hafeez, Sanaa
Al-Salem, Sultan M. M.
Villa, Alberto
Manos, George
Dimitratos, Nikolaos
Constantinou, Achilleas
[J]. MOLECULES, 2023, 28 (14):
[10] Multi-criteria decision framework for catalyst selection: Production of formic acid as a circular liquid organic hydrogen carrier in the hydrogen economy
Tekeli, Fatma Noyan
Filiz, Bilge Coskuner
Yoruklu, Hulya Civelek
Figen, Aysel Kanturk
[J]. JOURNAL OF CLEANER PRODUCTION, 2024, 452

← 1 2 3 4 5 →