Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d-4f discrete complexes

被引：452
|
作者：
Liu, Ke [1 ,2 ]
Shi, Wei [1 ,2 ]
Cheng, Peng [1 ,2 ]
机构：
[1] Nankai Univ, Dept Chem, Key Lab Adv Energy Mat Chem MOE, Tianjin 300071, Peoples R China
[2] Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China
来源：
COORDINATION CHEMISTRY REVIEWS | 2015年 / 289卷
关键词：
Heterometallic; Single-molecule magnets; Synthetic strategy; Structural diversity; Magnetism; DY-III; GD-III; CU-II; CRYSTAL-STRUCTURES; NI-II; CO-II; LANTHANIDE COMPLEXES; SLOW RELAXATION; TB-III; TETRANUCLEAR COMPLEXES;
D O I：
10.1016/j.ccr.2014.10.004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
3d-4f heterometallic discrete complexes have enjoyed increasing attraction in recent decades because of their potential advantages to create new single-molecule magnets: the moderate magnetic couplings between 3d and 4f spin carriers and significant single-ion magnetic anisotropies of 4f ions. Herein we review the synthetic strategy, structures and magnetic properties of 3d-4f discrete complexes. Particular attention is paid in this review to the examples showing dynamics of the magnetization. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：74 / 122
页数：49
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