Growth, thermal, optical and birefringence studies of semiorganic nonlinear optical thiosemicarbazide cadmium chloride monohydrate (TCCM) single crystals

被引：17
|
作者：
Maadeswaran, P. [1 ]
Thirumalairajan, S. [1 ]
Chandrasekaran, J. [1 ]
机构：
[1] Sri Ramakrishna Mission Vidyalaya Coll Arts & Sci, Dept Phys, Coimbatore 641020, Tamil Nadu, India
来源：
OPTIK | 2010年 / 121卷 / 09期
关键词：
Characterization; Growth from solution; Semiorganic; Nonlinear optical crystals; Birefringence;
D O I：
10.1016/j.ijleo.2008.09.041
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
A semiorganic nonlinear optical material (thiosemicarbazide cadmium chloride monohydrate) (TCCM) was synthesized and single crystals was grown from aqueous solution by slow evaporation method at ambient temperature. Crystal of average size up to 5 x 4 x 3 mm(3) were harvested and characterized by powder X-ray diffractometry (XRD) and Fourier transfer infrared (FUR) technique to confirm the identity of the compound formed. The thermal stability was analyzed by TG/DTA. The birefringence values (Delta(n)) were determined in the wavelength region 540-6500 angstrom. The second harmonic generation (SHG) from the materials was confirmed using Nd:YAG laser. (C) 2009 Elsevier GmbH. All rights reserved.
引用
收藏
页码：773 / 777
页数：5
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