Niobic acid nanoparticle catalysts for the aqueous phase transformation of glucose and fructose to 5-hydroxymethylfurfural

被引：26

作者：

Reche, Mariano Tapia ^{[1
]}

Osatiashtiani, Amin ^{[1
]}

Durndell, Lee J. ^{[1
]}

Isaacs, Mark A. ^{[1
]}

Silva, Angela ^{[2
]}

Lee, Adam F. ^{[1
]}

Wilson, Karen ^{[1
]}

机构：

[1] Aston Univ, European Bioenergy Res Inst, Birmingham B4 7ET, W Midlands, England

[2] Univ Fed Parana UFPR, Dept Quim, Lab Bioinorgan & Catalise, CP 19081, BR-81531990 Curitiba, Parana, Brazil

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2016年 / 6卷 / 19期

基金：

英国工程与自然科学研究理事会;

关键词：

CONVERSION; DEHYDRATION; OXIDE; BIOMASS; SUCROSE; SILICA; WATER; HMF; EFFICIENT; SITES;

D O I：

10.1039/c6cy01129b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A family of bulk and SBA-15 supported peroxo niobic acid sols were prepared by peptisation of niobic acid precipitates with H2O2 as heterogeneous catalysts for aqueous phase glucose and fructose conversion to 5-hydroxymethylfurfural (5-HMF). Niobic acid nanoparticles possess a high density of Bronsted and Lewis acid sites, conferring good activity towards glucose and fructose conversion, albeit with modest 5-HMF yields under mild reaction conditions (100 degrees C). Thermally-induced niobia crystallisation suppresses solid acidity and activity. Nanoparticulate niobic acid dispersed over SBA-15 exhibits pure Bronsted acidity and an enhanced Turnover Frequency for fructose dehydration.

引用

页码：7334 / 7341

页数：8

共 50 条

[1] Catalytic Conversion of Microcrystalline Cellulose to Glucose and 5-Hydroxymethylfurfural over a Niobic Acid Catalyst
Wen, Zhe
Yu, Linhao
Mai, Fuhang
Ma, Zewei
Chen, Hong
Li, Yongdan
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2019, 58 (38) : 17675 - 17681
[2] Polycationic nanostructured faujasite zeolite catalysts for glucose transformation into 5-hydroxymethylfurfural
Patrylak L.
Konovalov S.
Yakovenko A.
Pertko O.
Povazhnyi V.
Applied Nanoscience, 2023, 13 (8) : 5743 - 5754
[3] Polycationic nanostructured faujasite zeolite catalysts for glucose transformation into 5-hydroxymethylfurfural
Department of Catalytic Synthesis, V.P Kukhar Institute of Bioorganic Chemistry and Petrochemistry of NAS of Ukraine, Academician Kukhar Str., 1, Kyiv
02094, Ukraine
Appl. Nanosci. (Switzerland), 8 (5743-5754): : 5743 - 5754
[4] Fructose Dehydration to 5-Hydroxymethylfurfural over Solid Acid Catalysts in a Biphasic System
Ordomsky, Vitaly V.
van der Schaaf, John
Schouten, Jaap C.
Nijhuis, T. Alexander
CHEMSUSCHEM, 2012, 5 (09) : 1812 - 1819
[5] Performance of Dimethyl Sulfoxide and Bronsted Acid Catalysts in Fructose Conversion to 5-Hydroxymethylfurfural
Ren, Li-Ke
Zhu, Liang-Fang
Qi, Ting
Tang, Jin-Qiang
Yang, Hua-Qing
Hu, Chang-Wei
ACS CATALYSIS, 2017, 7 (03): : 2199 - 2212
[6] Direct conversion of glucose to 5-hydroxymethylfurfural using a mixture of niobic acid and niobium phosphate as a solid acid catalyst
Catrinck, Mariana N.
Ribeiro, Emerson S.
Monteiro, Robson S.
Ribas, Rogerio M.
Barbosa, Marcio H. P.
Teofilo, Reinaldo F.
FUEL, 2017, 210 : 67 - 74
[7] Effect of Formic Acid on Conversion of Fructose to 5-Hydroxymethylfurfural in Aqueous/Butanol Media
Jiang, Nan
Huang, Renliang
Qi, Wei
Su, Rongxin
He, Zhimin
BIOENERGY RESEARCH, 2012, 5 (02) : 380 - 386
[8] Direct Transformation of Fructose and Glucose to 5-Hydroxymethylfurfural in Ionic Liquids under Mild Conditions
Guo, Xiaoqian
Zhu, Changhui
Guo, Feng
BIORESOURCES, 2016, 11 (01): : 2457 - 2469
[9] Dehydration of Glucose and Fructose into 5-Hydroxymethylfurfural Catalyzed by Lewis Acid in Ionic Liquids
Tian Yukui
Deng Jin
Pan Tao
Guo Qingxiang
Fu Yao
CHINESE JOURNAL OF CATALYSIS, 2011, 32 (06) : 997 - 1002
[10] Effect of Formic Acid on Conversion of Fructose to 5-Hydroxymethylfurfural in Aqueous/Butanol Media
Nan Jiang
Renliang Huang
Wei Qi
Rongxin Su
Zhimin He
BioEnergy Research, 2012, 5 : 380 - 386

← 1 2 3 4 5 →