Crystallization kinetics of BaO-Al2O3-SiO2 glass-ceramics

被引：3

作者：

Lu Yu-Feng ^{[1
]}

Du Yong-Guo ^{[1
]}

Xiao Jia-Yu ^{[1
]}

Zhang Wei-Jun ^{[1
]}

Zheng Xiao-Hui ^{[1
]}

Zhou Wen-Yuan ^{[1
]}

机构：

[1] Natl Univ Def Technol, Coll Aerosp & Mat Engn, Changsha 410073, Peoples R China

来源：

JOURNAL OF INORGANIC MATERIALS | 2008年 / 23卷 / 02期

关键词：

glass-ceramics; celsian; crystallization; isoconversional method; Sestak-Berggren function;

D O I：

10.3724/SP.J.1077.2008.00315

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

BaO-Al2O3-SiO2(BAS) glass-ceramics with stoichiometric and off-stoichiometric celsian composition were fabricated. Crystallization characters of two groups of BaO-Al2O3-SiO2 (BAS) glass-ceramics were investigated by differential scanning calorimetry (DSC), X-ray diffraction (XRD), iso-conversional method and multiple linear regression method. The autocatalytic kinetic model (Sestak-Berggren function) was found to be the most proper description of the studied processes for all glass investigated. Doping with ZrO2 or increasing mass fraction of BaO accelerates the crystallization process of hexagonal-BaAl2Si2O8 in BAS glass-ceramics with stoichiometric celsian composition whose viscosity is high. Moreover, the lower the temperature gets, or the higher the crystallinity gets, the more obvious the accelerating effect gets. While doping with ZrO2 decelerates the crystallization process of hexagonal-BaAl2Si2O8 in BAS glass-ceramics with off-stoichiometric celsian composition whose viscosity is low. Moreover, the higher the temperature gets, the more obvious the decelerating effect gets.

引用

页码：315 / 321

页数：7

共 21 条

[1] Crystallization kinetics of a solid oxide fuel cell seal glass by differential thermal analysis
Bansal, NP
Gamble, EA
[J]. JOURNAL OF POWER SOURCES, 2005, 147 (1-2) : 107 - 115
[2] Design and optimisation of glass-celsian composites
Cannillo, V
Carlier, E
Manfredini, T
Montorsi, M
Siligardi, C
[J]. COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2006, 37 (01) : 23 - 30
[3] Low-temperature synthesis of NaNbO3 nanopowders and their thin films from a novel carbon-free precursor
Cheng, ZX
Ozawa, K
Osada, M
Miyazaki, A
Kimura, H
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2006, 89 (04) : 1188 - 1192
[4] Corral J. S. M., 1978, Transactions and Journal of the British Ceramic Society, V77, P40
[5] Crystallization kinetic of glass particles prepared from a mixture of coal ash and soda-lime cullet glass
Francis, AA
Rawlings, RD
Sweeney, R
Boccaccini, AR
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2004, 333 (02) : 187 - 193
[6] Limitations of the Augis and Bennett method for kinetic analysis of the crystallization of glasses and conditions for correct use
Gotor, FJ
Criado, JM
Málek, J
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2001, 84 (08) : 1797 - 1802
[7] Kinetics of thermal degradation applied to starches from different botanical origins by non-isothermal procedures
Guinesi, Luciana S.
da Roz, Alessandra L.
Corradini, Elisangela
Mattoso, Luiz Henrique C.
Teixeira, Eliangela de M.
Curvelo, Antonio A. da S.
[J]. THERMOCHIMICA ACTA, 2006, 447 (02) : 190 - 196
[8] THERMAL-ANALYSIS OF NONISOTHERMAL CRYSTALLIZATION KINETICS IN GLASS FORMING LIQUIDS
HENDERSON, DW
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1979, 30 (03) : 301 - 315
[9] Preparation, thermal decomposition and lifetime of Eu(III)-phenanthroline complex doped xerogel
Hong, JH
Yi, TY
Min, J
Cong, CJ
Zhang, KL
[J]. THERMOCHIMICA ACTA, 2006, 440 (01) : 31 - 35
[10] Non-isothermal crystallization and thermal transitions of a biodegradable, partially hydrolyzed poly(vinyl alcohol)
Huang, He
Gu, Lixia
Ozaki, Yukihiro
[J]. POLYMER, 2006, 47 (11) : 3935 - 3945

← 1 2 3 →