Impact of carbon dioxide on the activity and selectivity of supported palladium catalysts for carbon monoxide hydrogenation

被引:0
|
作者
Filonenko, GV [1 ]
机构
[1] NATL ACAD SCI UKRAINE,LV PISARZHEVSKY PHYS CHEM INST,KIEV,UKRAINE
关键词
D O I
10.1177/026361749601400502
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The introduction of 1.5 vol.% carbon dioxide into the reaction mixture (CO/H-2 = 1:2) is shown to accelerate the rate of formation of methanol and the selectivity towards oxygen-containing products over palladium catalysts supported on oxides of various chemical natures. The maximum degree of impact of CO2 was observed over palladium supported on magnesia and zirconia.
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页码:279 / 285
页数:7
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