Catalytic hydrogenation of carbon dioxide to formic acid in aqueous solutions of polyethylene oxide

被引：0
|
作者：
Karakhanov, EA [1 ]
Egazar'yants, SV
Kardashev, SV
Maksimov, AL
Minos'yants, SS
Sedykh, AD
机构：
[1] Moscow MV Lomonosov State Univ, Moscow 119899, Russia
[2] OAO Gazprom, Moscow, Russia
来源：
PETROLEUM CHEMISTRY | 2001年 / 41卷 / 04期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The catalytic hydrogenation of carbon dioxide to formic acid in aqueous solutions of polyethylene oxide in the presence of various amines was studied. The rhodium complex formed in situ under the reaction conditions from rhodium(III) chloride and triphenylphosphine was used as the catalyst. The dependence of the yield of formic acid on the amine nature and on the metal and polymer concentration was studied.
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页码：268 / 271
页数：4
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