Catalytic C-F bond activation of nonactivated monofluoroarenes

被引：103
|
作者：
Young, RJ [1 ]
Grushin, VV [1 ]
机构：
[1] Dupont Co, Dept Cent Res & Dev, Expt Stn, Wilmington, DE 19880 USA
来源：
ORGANOMETALLICS | 1999年 / 18卷 / 03期
关键词：
D O I：
10.1021/om980887w
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Catalytic hydrogenolysis of the C-F bond in most unreactive monofluoroarenes readily occurs under mild conditions, in the presence of homogeneous and/or heterogeneous Rh catalysts generated from [(Cy3P)(2)-Rh(H)Cl-2], H-2, and aqueous alkali.
引用
收藏
页码：294 / 296
页数：3
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