Nitrogen-Doped Ordered Mesoporous Anatase TiO2 Nanofibers as Anode Materials for High Performance Sodium-Ion Batteries

被引:146
|
作者
Wu, Ying [1 ,2 ,3 ]
Liu, Xiaowu [1 ]
Yang, Zhenzhong [4 ]
Gu, Lin [4 ,5 ]
Yu, Yan [1 ,2 ,3 ]
机构
[1] Univ Sci & Technol China, Dept Mat Sci & Engn, Chinese Acad Sci, Key Lab Mat Energy Convers, Hefei 230026, Anhui, Peoples R China
[2] Nankai Univ, Minist Educ, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China
[3] Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
[4] Chinese Acad Sci, Inst Phys, Beijing Lab Electron Microscopy, Beijing 100190, Peoples R China
[5] Collaborat Innovat Ctr Quantum Matter, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
LI-ION; LITHIUM BATTERIES; ELECTROCHEMICAL PERFORMANCE; PHOTOCATALYTIC ACTIVITY; CARBON NANOFIBERS; RATE CAPABILITY; SUPERIOR ANODE; HIGH-CAPACITY; BLACK TIO2; NANOPARTICLES;
D O I
10.1002/smll.201600606
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nitrogen-doped ordered mesoporous TiO2 nanofi bers (N-MTO) have been fabricated by electrospinning and subsequent nitridation treatment. The N-doping in TiO2 leads to the formation of Ti3+, resulting in the improved electron conductivity of TiO2. In addition, one-dimensional (1D) N-MTO nanostructure possesses very short diffusion length of Na+/e(-) in N-MTO, easy access of electrolyte, and high conductivity transport of electrons along the percolating fibers. The N-MTO shows excellent sodium storage performance.
引用
收藏
页码:3522 / 3529
页数:8
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