New approach to phosphinoalkynes based on Pd- and Ni-catalyzed cross-coupling of terminal alkynes with chlorophosphanes

被引：58

作者：

Beletskaya, IP ^{[1
]}

Afanasiev, VV ^{[1
]}

Kazankova, MA ^{[1
]}

Efimova, IV ^{[1
]}

机构：

[1] MSU, Dept Chem, Moscow 119992, Russia

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 23期

关键词：

D O I：

10.1021/ol035562c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first example of direct phosphination of terminal alkynes with chlorophosphanes catalyzed by Ni or Pd complexes is described. Both aromatic and aliphatic terminal acetylenes undergo the coupling reaction to give corresponding coupling product in high yield.

引用

页码：4309 / 4311

页数：3

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