Solvent extraction behavior of plutonium (IV) ions in the presence of simple hydroxamic acids

被引：47
|
作者：
Carrott, M. J.
Fox, O. D.
Maher, C. J.
Mason, C.
Taylor, R. J.
机构：
[1] Pacific NW Natl Lab, Richland, WA 99352 USA
[2] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA
来源：
SOLVENT EXTRACTION AND ION EXCHANGE | 2007年 / 25卷 / 06期
关键词：
formohydroxamic acid; acetohydroxamic acid; advanced Purex; distribution coefficient; stability constant; actinide separations;
D O I：
10.1080/07366290701634560
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Formo- and aceto-hydroxamic acids are very effective reagents for stripping Pu(IV) ions from a tri-butyl phosphate phase into nitric acid. Distribution data for Pu(IV) in the presence of these hydroxamate ions have been obtained and trends established. The affinity of aceto-hydroxamic acid for Pu(IV) ions and its selectivity over U(VI) ions is demonstrated by the values of the stability constants in HClO4. These data support the applications of simple hydroxamic acids in advanced Purex-type solvent extraction systems.
引用
收藏
页码：723 / 745
页数：23
相关论文
共 50 条
  • [1] Solvent extraction behavior of neptunium (IV) ions between nitric acid and diluted 30% tri-butyl phosphate in the presence of simple hydroxamic acids
    Taylor, R. J.
    Sinkov, S. I.
    Choppin, G. R.
    May, I.
    SOLVENT EXTRACTION AND ION EXCHANGE, 2008, 26 (01) : 41 - 61
  • [2] Oxidation-reduction reactions of simple hydroxamic acids and plutonium(IV) ions in nitric acid
    Carrott, M. J.
    Fox, O. D.
    LeGurun, G.
    Jones, C. J.
    Mason, C.
    Taylor, R. J.
    Andrieux, F. P. L.
    Boxall, C.
    RADIOCHIMICA ACTA, 2008, 96 (06) : 333 - 343
  • [3] Plutonium distribution in the presence of hydroxamic acids
    Fox, OD
    Taylor, RJ
    PLUTONIUM FUTURES - THE SCIENCE, 2003, 673 : 282 - 282
  • [4] Modelling Np(IV) Solvent Extraction between 30% Tri-Butyl Phosphate and Nitric Acid in the Presence of Simple Hydroxamic Acids
    Sarsfield, Mark J.
    Sims, Howard E.
    Taylor, Robin J.
    SOLVENT EXTRACTION AND ION EXCHANGE, 2011, 29 (01) : 49 - 71
  • [5] SOLVENT-EXTRACTION OF METALS WITH HYDROXAMIC ACIDS
    VERNON, F
    KHORASSANI, JH
    TALANTA, 1978, 25 (07) : 410 - 412
  • [6] COMPLEXATION STUDIES OF DIALKYLTIN(IV) IONS WITH HYDROXAMIC ACIDS
    NARULA, CK
    GUPTA, VD
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1980, 19 (05): : 491 - 493
  • [7] THE EFFECT OF SUBSTITUENTS ON THE EXTRACTION BEHAVIOR OF HYDROXAMIC ACIDS
    HOJJATIE, M
    CECCONIE, T
    FREISER, H
    ANALYTICA CHIMICA ACTA, 1987, 199 : 49 - 57
  • [8] EXTRACTION OF THE TITANIUM COMPLEXES OF HYDROXAMIC ACIDS IN THE PRESENCE OF THIOCTYLAMINE
    ZMIEVSKAYA, OR
    FADEEVA, VI
    JOURNAL OF ANALYTICAL CHEMISTRY OF THE USSR, 1979, 34 (05): : 702 - 705
  • [9] Solvent extraction of osmium(IV) from sulfuric acid solutions in the presence of chloride ions
    Mayboroda, A
    Troshkina, ID
    Chekmarev, AM
    Lang, H
    HYDROMETALLURGY, 2003, 68 (1-3) : 141 - 150
  • [10] Solvent extraction of plutonium(IV) in monoamide - ammonium ionic liquid mixture
    Rout, Alok
    Chatterjee, K.
    Venkatesan, K. A.
    Sahu, K. K.
    Antony, M. P.
    Rao, P. R. Vasudeva
    SEPARATION AND PURIFICATION TECHNOLOGY, 2016, 159 : 43 - 49
12345