Cellulose wrapped silver nanowire film with enhanced stability for transparent wearable heating and electromagnetic interference shielding

被引:21
|
作者
Zou, Xiuxiu [1 ]
Zhao, Mengke [1 ]
Shen, Kuizhong [1 ]
Huang, Chen [1 ]
Wu, Yiqiang [2 ]
Fang, Guigan [1 ]
机构
[1] Chinese Acad Forestry, Inst Chem Ind Forest Prod, Jiangsu Prov Key Lab Biomass Energy & Mat, Nanjing 210042, Peoples R China
[2] Cent South Univ Forestry & Technol, Sch Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
Silver nanowire; Hydroxy propyl methyl cellulose; Embedded double-layered structure; High stability; Light transmittance; Electromagnetic interference shielding; CARBON NANOTUBES; CONDUCTING FILMS; COMPOSITES; ELECTRODE; ULTRASMOOTH; OXIDATION;
D O I
10.1016/j.jallcom.2022.164360
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Flexible, transparent and conductive materials applied to the electromagnetic interference (EMI) shielding of foldable and wearable devices is urgently demanded in fifth-generation internet era. However, it is still a great challenge to realize excellent EMI shielding effectiveness (EMI SE) while maintaining high light transmittance. Herein, a double-layered structure strategy was proposed to prepare transparent and conductive silver nanowires (AgNWs) film with outstanding EMI SE. Specifically, the AgNWs network was partially embedded to hydroxy propyl methyl cellulose (HPMC) coating to enhance greatly its connectivity and integrity. As a result, the AgNWs/HPMC film showed a high transmittance of 90.55% at 550 nm and a sheet resistance of 11.62 Omega/sq, much better than other reported AgNW composite films so far. Meanwhile, the structural design also contributed to a high EMI SE of 45.79 dB. Meanwhile, it exhibited an enhanced conductive stability during bending test and harsh environment, such as full-oxygen, thermal and cold environment. Moreover, the multifunctional AgNWs/HPMC film presented remarkable thermal management performances including safe heating temperature (~ 71.3 degrees C) at high supplied voltages (7 V), ultra rapid response time (~ 11 s), long-term heating stability and reliability. This work presented a facile and scalable approach to obtain the flexible AgNWs/HPMC film with high light transmittance and high EMI SE, promising for the EMI shielding foldable and homoiothermy wearable system for human.(c) 2022 Elsevier B.V. All rights reserved.
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页数:12
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