Beckmann rearrangement of ketoximes to lactams by triphosphazene catalyst

被引：169
|
作者：
Hashimoto, Masaharu [1 ,2 ]
Obora, Yasushi [1 ,2 ]
Sakaguchi, Satoshi [1 ,2 ]
Ishii, Yasutaka [1 ,2 ]
机构：
[1] Kansai Univ, High Technol Res Ctr, Suita, Osaka 5648680, Japan
[2] Kansai Univ, Fac Chem Mat & Bioengn, Dept Chem & Mat Engn, Suita, Osaka 5648680, Japan
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 07期
关键词：
D O I：
10.1021/jo702277g
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Triphosphazene, 1,3,5-triazo-2,4,6-triphosphorine-2,2,4,4,6,6-chloride (TAPC), was found to be an efficient catalyst for the Beckmann rearrangement of cyclohexanone oxime and cyclododecanone oxime to E-caprolactam and laurolactam, which are raw materials of nylon-6 and nylon-12, respectively.
引用
收藏
页码：2894 / 2897
页数：4
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