A promising method for phosphinidene generation:: Complexes of phosphinidenes with N-donor ligands

被引：8

作者：

Benko, Zoltan ^{[2
]}

Gudat, Dietrich ^{[1
]}

Nyulaszi, Laszlo ^{[2
]}

机构：

[1] Univ Stuttgart, Inst Inorgan Chem, D-70569 Stuttgart, Germany

[2] Budapest Univ Technol & Econ, Dept Inorgan & Analyt Chem, H-1111 Budapest, Hungary

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2008年 / 14卷 / 03期

关键词：

aromaticity; density functional calculations; dissociation; N-donor ligands; phosphinidene;

D O I：

10.1002/chem.200701077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,3,2-diazaphospholenes and related compounds can formally be regarded as complexes of phosphinidenes (R-P) with 1,4-diazabutadienes. The dissociation Gibbs free energies of these "complexes" were calculated by using density functional theory (B3LYP/3-21G(*) and B3LYP/6-311+G**). The dissociation Gibbs free energies show systematic dependence on the phosphorus substituent as well as on the stability of the N-donor ligand formed as a byproduct. The thermodynamics and kinetics of the dissociations were thoroughly examined. The results allow us to conclude that novel routes of phosphinidene generation can be developed.

引用

页码：902 / 908

页数：7

共 50 条

[1] Metal Complexes with N-donor Ligands
Kotai, Laszlo
[J]. INORGANICS, 2024, 12 (05)
[2] Yttrium complexes with N-donor ligands
Petrosyants, S. P.
Ilyukhin, A. B.
[J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2014, 40 (11) : 825 - 830
[3] Yttrium complexes with N-donor ligands
S. P. Petrosyants
A. B. Ilyukhin
[J]. Russian Journal of Coordination Chemistry, 2014, 40 : 825 - 830
[4] Metal saccharinates and their complexes with N-donor ligands
Jovanovski, G
[J]. CROATICA CHEMICA ACTA, 2000, 73 (03) : 843 - 868
[5] Uranium complexes of multidentate N-donor ligands
Sessler, Jonathan L.
Melfi, Patricia J.
Pantos, G. Dan
[J]. COORDINATION CHEMISTRY REVIEWS, 2006, 250 (7-8) : 816 - 843
[6] COMPLEXES OF LEAD(IV) WITH N-DONOR LIGANDS
BIRADAR, NS
KULKARNI, VH
SIRMOKAD.NN
[J]. INDIAN JOURNAL OF CHEMISTRY, 1971, 9 (10): : 1162 - &
[7] Copper Complexes of N-Donor Ligands as Artificial Nucleases
Wende, Christian
Luedtke, Carsten
Kulak, Nora
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, (16) : 2597 - 2612
[8] Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands
A. V. Maleeva
O. Yu. Trofimova
I. A. Yakushev
R. R. Aysin
A. V. Piskunov
[J]. Russian Journal of Coordination Chemistry, 2023, 49 : 420 - 428
[9] MIXED COMPLEXES OF NICKEL(II) WITH N-DONOR LIGANDS
PONTICELLI, G
PRETI, C
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (06): : 708 - +
[10] Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands
Maleeva, A. V.
Trofimova, O. Yu.
Yakushev, I. A.
Aysin, R. R.
Piskunov, A. V.
[J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2023, 49 (07) : 420 - 428

← 1 2 3 4 5 →