Enantioselective oxidations by the diketocamphane monooxygenase isozymes from Pseudomonas putida

被引：21
|
作者：
Beecher, J
Grogan, G
Roberts, S
Willetts, A
机构：
[1] UNIV EXETER,DEPT BIOL SCI,EXETER EX4 4QG,DEVON,ENGLAND
[2] UNIV LIVERPOOL,DEPT CHEM,LIVERPOOL L69 3BX,MERSEYSIDE,ENGLAND
来源：
BIOTECHNOLOGY LETTERS | 1996年 / 18卷 / 05期
关键词：
D O I：
10.1007/BF00140205
中图分类号：
Q81 [生物工程学（生物技术）]; Q93 [微生物学];
学科分类号：
071005 ; 0836 ; 090102 ; 100705 ;
摘要：
2,5-Diketocamphane 1,2-monooxygenase and 3,6-diketocamphane 1,6-monooxygenase isolated from (+/-)-camphor grown Pseudomonas putida NCIMB 10007 catalysed two different types of Baeyer-Villiger oxidations. The former isozyme biotransformed various bicyclic [3.2.0] ketones and aryl alkyl sulfides with consistently greater regio- and/or enantioselectivity, yielding lactone and sulfoxide products with enantiomeric excesses > 55%.
引用
收藏
页码：571 / 576
页数：6
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