Leaching kinetics of cadmium from scallop waste by dilute sulfuric acid solution

被引:4
|
作者
Huang, Kai [1 ]
Ghimire, Kedar Nath [1 ]
Inoue, Katsutoshi [1 ]
Ohto, Keisuke [1 ]
Kawakita, Hidetaka [1 ]
Harada, Hiroyuki [1 ]
Morita, Minoru [2 ]
机构
[1] Saga Univ, Dept Appl Chem, Saga, Japan
[2] Unirex Corp, Nishi Ku, Hokkaido 0630837, Japan
关键词
leaching kinetics; cadmium; uro; shrinking core model;
D O I
10.1252/jcej.07WE020
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The leaching kinetics of cadmium from scallop waste in dilute sulfuric acid was investigated by examining the effect of temperature (293-333 K), pH (1.5-2.5), and particle size on the leaching rate. The kinetics of the cadmium extraction process with intraparticle diffusion was reasonably interpreted according to the shrinking core model as a rate-determining step in accordance with the value of the activation energy, 15.9 kJ/mol. Increasing temperature, and decreasing pH and particle size positively influence the extraction of cadmium from the uro.
引用
收藏
页码:786 / 791
页数:6
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