Preparation and properties of films based on chitosan and polyelectrolyte complexes of chitosan with carboxymethylchitin

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作者
Ageev, EP [1 ]
Vikhoreva, GA
Gal'braikh, LS
Matushkina, NN
Chaika, EM
Jaminsky, IV
机构
[1] Moscow MV Lomonosov State Univ, Dept Chem, Vorobevy Gory, Moscow 119899, Russia
[2] Moscow State Text Acad, Moscow 117918, Russia
[3] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia
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中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The mechanical, sorption, and permselective properties of membranes based on chitosan and chitosan complexes with carboxymethylchitin were studied as dependent on the polymer structure and its changes caused by water-temperature treatment. It was shown that the selectivity of chitosan films in the pervaporation of water-isopropanol mixtures increases with an increase in the degree of the polymer deacetylation, while the selectivity of films based on chitosan complexes with carboxymethylchitin enhances as their composition approaches stoichiometric and as a result. of the water-temperature treatment.
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页码:1198 / 1204
页数:7
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