Synthesis, characterization and antimicrobial activity of new cobalt (II), nickel (II) and copper (II) complexes with 2-(2-hydroxy-1, 2-diphenylethylideneamino) benzoic acid

被引:16
|
作者
Manikshete, A. H. [1 ]
Sarsamkar, S. K. [1 ]
Deodware, S. A. [1 ]
Kamble, V. N. [1 ]
Asabe, M. R. [1 ]
机构
[1] Walchand Coll Arts & Sci, Dept Chem, Solapur 413006, Maharashtra, India
关键词
Transition metal complexes; 2-Amino benzoic acid; Schiff base; Antifungal and antibacterial activity; SPECTRAL CHARACTERIZATION; METAL-COMPLEXES; SCHIFF-BASES; CO(II); NI(II); CU(II); THIOSEMICARBAZONE; ZINC(II);
D O I
10.1016/j.inoche.2011.01.016
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The new Schiff base ligand 2-(2-hydroxy-1, 2-diphenylethylideneamino) benzoic acid [HL] and its Co(II), Ni(II) and Cu(II) metal complexes were synthesized. The ligand and metal complexes were characterized by elemental analysis, UV-visible, IR, H-1 NMR spectroscopy, thermal studies and magnetic susceptibility measurement. The ligand [HL] was synthesized by condensation of benzoin and 2-amino benzoic acid. On the basis of electronic spectral data and magnetic susceptibility measurement the octahedral geometry has been proposed for Cu(II). Ni(II) and Co(II) complexes. The ligand and metal (II) complexes were also screened for their antimicrobial activity against microorganisms Staphylococcus aureus and Pseudomonas aeruginosa and antifungal activity against the fungi Candida albicans and Aspergillus niger. (C) 2011 Elsevier B.V. All rights reserved.
引用
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页码:618 / 621
页数:4
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