Conductivity, morphology, interfacial chemistry, and stability of poly(3,4-ethylene dioxythiophene)-poly(styrene sulfonate): A photoelectron spectroscopy study

被引：477
|
作者：
Crispin, X [1 ]
Marciniak, S
Osikowicz, W
Zotti, G
Van der Gon, AWD
Louwet, F
Fahlman, M
Groenendaal, L
De Schryver, F
Salaneck, WR
机构：
[1] Linkoping Univ, Dept Phys & Measurement Technol, S-58183 Linkoping, Sweden
[2] Inst Consiglio Nazl Ric Energet & Interfasi, Co Stati Uniti 4, I-35127 Padua, Italy
[3] Eindhoven Univ Technol, Fac Appl Phys, NL-5600 MB Eindhoven, Netherlands
[4] Agfa Gevaert NV, R&D Mat Res, Dept Chem, B-2640 Mortsel, Belgium
[5] Linkoping Univ, Dept Sci & Technol, S-60174 Norrkoping, Sweden
[6] Katholieke Univ Leuven, Afdeling Fotochem & Spect, B-3001 Heverlee, Belgium
来源：
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS | 2003年 / 41卷 / 21期
关键词：
ESCA/XPS; poly(3,4-ethylene dioxythiophene); conductivity; degradation; interfacial chemistry; conducting polymers;
D O I：
10.1002/polb.10659
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
X-ray photoelectron spectroscopy (XPS) has been used to characterize poly(3,4-ethylene dioxythiophene)-poly(styrene sulfonate) (PEDT/PSS), one of the most common electrically conducting organic polymers. A correlation has been established between the composition, morphology, and polymerization mechanism, on the one hand, and the electric conductivity of PEDT/PSS, on the other hand. XPS has been used to identify interfacial reactions occurring at the polymer-on-ITO and polymer-on-glass interfaces, as well as chemical changes within the polymer blend induced by electrical stress and exposure to ultraviolet light. (C) 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 2561-2583, 2003
引用
收藏
页码：2561 / 2583
页数：23
相关论文
共 50 条
  • [1] Study of poly (3,4-ethylene dioxythiophene):: Poly (styrene sulfonate) by in-situ resonance Raman spectroscopy
    Lin, HB
    Xu, XX
    Wang, B
    Wu, BL
    Xu, JL
    Yu, G
    Zhang, CZ
    [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26 (04) : 646 - 648
  • [2] Structure of films of poly(3,4-ethylene dioxythiophene)-poly(styrene sulfonate) crosslinked with glycerol
    Rodriguez, Ana B.
    Voigt, Monika M.
    Martin, Simon J.
    Whittle, Tracie J.
    Dalgliesh, Robert M.
    Thompson, Richard L.
    Lidzey, David G.
    Geoghegan, Mark
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (48) : 19324 - 19330
  • [3] Study of poly (3, 4-ethylene dioxythiophene):Poly (styrene sulfonate) by in-situ resonance Raman spectroscopy
    Lin, Hai-Bo
    Xu, Xiao-Xuan
    Wang, Bin
    Wu, Bin-Lin
    Xu, Jia-Lin
    Yu, Gang
    Zhang, Cun-Zhou
    [J]. Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis, 2006, 26 (04): : 646 - 648
  • [4] Measuring optical anisotropy in poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) films with added graphene
    Isoniemi, Tommi
    Tuukkanen, Sampo
    Cameron, David C.
    Simonen, Janne
    Toppari, J. Jussi
    [J]. ORGANIC ELECTRONICS, 2015, 25 : 317 - 323
  • [5] Controlling the surface composition of poly(3,4-ethylene dioxythiophene)poly(styrene sulfonate) blends by heat treatment
    Jukes, PC
    Martin, SJ
    Higgins, AM
    Geoghegan, M
    Jones, RAL
    Langridge, S
    Wehrum, A
    Kirchmeyer, S
    [J]. ADVANCED MATERIALS, 2004, 16 (9-10) : 807 - +
  • [6] Poly(3,4-Ethylene Dioxythiophene)/Poly(Styrene Sulfonate) Electrodes in Electrochemical Cells for Harvesting Waste Heat
    Wang, Ying
    Mukaida, Masakazu
    Kirihara, Kazuhiro
    Lyu, Lingyun
    Wei, Qingshuo
    [J]. ENERGY TECHNOLOGY, 2020, 8 (05)
  • [7] Fabrication of highly electrical synthetic leather with polyurethane/poly(3,4-ethylene dioxythiophene)/poly(styrene sulfonate)
    Shin, Eun Joo
    Han, Sung Soo
    Choi, Soon Mo
    [J]. JOURNAL OF THE TEXTILE INSTITUTE, 2018, 109 (02) : 241 - 247
  • [8] Influence of a water rinse on the structure and properties of poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) films
    DeLongchamp, DM
    Vogt, BD
    Brooks, CM
    Kano, K
    Obrzut, J
    Richter, CA
    Kirillov, OA
    Lin, EK
    [J]. LANGMUIR, 2005, 21 (24) : 11480 - 11483
  • [9] Poly(3,4-ethylene dioxythiophene):Poly(styrene sulfonate)的共振拉曼光谱研究
    林海波
    徐晓轩
    王斌
    吴彬麟
    许家林
    俞钢
    张存洲
    [J]. 光谱学与光谱分析, 2006, (04) : 646 - 648
  • [10] The synthesis and capacitive properties of poly(3,4-ethylene dioxythiophene)/poly(styrene-sulfonate) and poly (acrylamide) conducting hydrogels
    Aouada, Fauze A.
    de Moura, Marcia R.
    Girotto, Emerson M.
    Rubira, Adley F.
    Muniz, Edvani C.
    [J]. E-POLYMERS, 2007,
12345