The Influence of Water and Temperature on the Solubility of C60 in Pyridine Solution

被引：2
|
作者：
Mahdaoui, Dorra [1 ,2 ]
Abderrabba, Manef [1 ]
Hirata, Chika [2 ]
Wakahara, Takatsugu [2 ]
Miyazawa, Kun'ichi [2 ]
机构：
[1] Univ Carthage, Preparatory Inst Sci & Tech Studies, Lab Mol Mat & Applicat, BP 51 2075, Tunis, Tunisia
[2] NIMS, Fullerene Engn Grp, Mat Proc Unit, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan
来源：
JOURNAL OF SOLUTION CHEMISTRY | 2016年 / 45卷 / 08期
基金：
日本学术振兴会;
关键词：
Fullerene; Pyridine; Solubility; Kinetic; Water; Temperature; FULLERENE C-60; SOLVENT POLARITY; AGGREGATION; NANOTUBES; DONORS; C-70;
D O I：
10.1007/s10953-016-0497-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The dependence of Fullerene's solubility on both molecular structure of the solvent and temperature must be understood in order to optimize the growth condition of C-60 nanotubes (C60NTs) prepared by a modified liquid-liquid interfacial precipitation method. We explore the influence of small amounts of water dissolved in pyridine on the solubility of C-60. We observe a decreasing solubility of Fullerene as a function of increasing water content. This result is confirmed by a kinetics study of the Fullerene C-60 and pyridine reaction in the presence of water. The activation energy of C-60 in pyridine solution become important with increasing water content. We have also investigated the effect of incubation temperature on the solubility of C-60 in pyridine solution. The solubility of Fullerene is maximum when the incubation temperature is 273 K.
引用
收藏
页码：1158 / 1170
页数：13
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