Ligand-free heck reaction:: Pd(OAc)2 as an active catalyst revisited

被引：248
|
作者：
Yao, QW [1 ]
Kinney, EP
Yang, Z
机构：
[1] No Illinois Univ, Michael Faraday Labs, Dept Chem & Biochem, De Kalb, IL 60115 USA
[2] Shanxi Inst Chem Engn, Shanxi 030024, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 19期
关键词：
D O I：
10.1021/jo034646w
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium acetate was shown to be an extremely active catalyst for the Heck reaction of aryl bromides. Both the base and the solvent were found to have a fundamental influence on the efficiency of the reaction, with K3PO4 and N,N-dimethylacetamide being the optimal base and solvent, respectively.
引用
收藏
页码：7528 / 7531
页数：4
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