Synthesis of dihalomethyl compounds of indium, X(2)InCHX(2), and a study of their coordination chemistry

被引：12
|
作者：
dosSantos, JE
Peppe, C
Brown, MA
Tuck, DG
机构：
[1] UNIV FED PARAIBA,DEPT QUIM,CCEN,BR-58059900 JOAO PESSOA,PARAIBA,BRAZIL
[2] UNIV WINDSOR,DEPT CHEM & BIOCHEM,WINDSOR,ON N9B 3P4,CANADA
来源：
ORGANOMETALLICS | 1996年 / 15卷 / 09期
关键词：
D O I：
10.1021/om9506835
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Indium(I) halides, InX (X = Cl, Br, I), react with haloforms, CHX(3), to give X(2)InCHX(2) derivatives. Treatment of the latter with (C2H5)(4)N(+)X(-) gives the 1:1 electrolytes [(C2H5)(4)N][X(3)InCHX(2)], but with neutral ligands L (L = dimethylsulfoxide (dmso), 1,1,3,3-tetramethyl-2-thiourea (tmtu), triphenylphosphine), the products were the adducts of the corresponding indium trihalide, InX(3)L(n) (X = Cl, L = tmtu, n = 2; X = Cl, L = Ph(3)P, n = 2; X = Cl, L = dmso, n = 3; X = Br, L = dmso, n = 3; X = I, L = Ph(3)P, n = 2: X = I, L = tmtu, n = 1). [(C2H5)(4)N][X(3)InCHX(2)] (X = Br, I) reacts with InX to give, after the addition of (C2H5)(4)NX, the salts [(C2H5)(4)N](2)[X(3)InCHXInX(3)].
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页码：2201 / 2204
页数：4
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