Synthesis of β,β-Azo Bridged Diporphyrins

被引:0
|
作者
Huang, Qimao [1 ]
Pan, Wei [1 ]
Li, Qing [1 ]
Wang, Siwei [1 ]
Li, Zhiyuan [1 ]
Pan, Zhiquan [1 ]
机构
[1] Wuhan Inst Technol, Minist Educ, Key Lab Green Chem Proc, Wuhan 430073, Peoples R China
关键词
diporphyrins; azo bridge; synthesis; characterization; PHOTODYNAMIC THERAPY; PORPHYRIN DIMERS;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Novel beta,beta-azo bridged diporphyrins were synthesized through 2-nitro-5,10,15,20-tetraphenylporphyrin coupled with sodium borohydride/Pd-C as a reduction system, and their structures were characterized by UV-vis, H-1 NMR, IR, mass spectra, Raman spectroscopy and elementary analysis. Their cleavage ability to pBR322 plasmid DNA had been tested by gel electrophoresis.
引用
收藏
页码:336 / 340
页数:5
相关论文
共 20 条
  • [1] Synthetic routes to multiporphyrin arrays
    Burrell, AK
    Officer, DL
    Plieger, PG
    Reid, DCW
    [J]. CHEMICAL REVIEWS, 2001, 101 (09) : 2751 - 2796
  • [2] Targeted proton delivery in the catalyzed reduction of oxygen to water by bimetallic Pacman porphyrins
    Chang, CJ
    Loh, ZH
    Shi, CN
    Anson, FC
    Nocera, DG
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (32) : 10013 - 10020
  • [3] π-Metal complexes of tetrapyrrolic systems. A novel coordination mode in "porphyrin-like'' chemistry
    Cuesta, Luciano
    Sessler, Jonathan L.
    [J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (09) : 2716 - 2729
  • [4] A new micro/nanoencapsulated porphyrin formulation for PDT treatment
    Deda, Daiana K.
    Uchoa, Adjaci F.
    Carita, Eduardo
    Baptista, Mauricio S.
    Toma, Henrique E.
    Araki, Koiti
    [J]. INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2009, 376 (1-2) : 76 - 83
  • [5] Photodynamic therapy for cancer
    Dolmans, DEJGJ
    Fukumura, D
    Jain, RK
    [J]. NATURE REVIEWS CANCER, 2003, 3 (05) : 380 - 387
  • [6] SYNTHESIS AND CD SPECTRUM OF CHIRAL PORPHYRIN DIMER
    EMA, T
    NEMUGAKI, S
    TSUBOI, S
    UTAKA, M
    [J]. TETRAHEDRON LETTERS, 1995, 36 (33) : 5905 - 5908
  • [7] Design and synthesis of porphyrin-containing catenanes and rotaxanes
    Faiz, Jonathan A.
    Heitz, Valerie
    Sauvage, Jean-Pierre
    [J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (02) : 422 - 442
  • [8] RESONANCE RAMAN OBSERVATION OF SURFACE CARBONYL GROUPS ON CARBON ELECTRODES FOLLOWING DINITROPHENYLHYDRAZINE DERIVATIZATION
    FRYLING, MA
    ZHAO, J
    MCCREERY, RL
    [J]. ANALYTICAL CHEMISTRY, 1995, 67 (05) : 967 - 975
  • [9] HERMANN K, 1993, TETRAHEDRON, V49, P9489
  • [10] Huang QM, 2010, CHEM J CHINESE U, V31, P1309