Heteroatomic Si/Ge Zintl Clusters: Single-Crystal Structure Determination of Rb4[Si7.8Ge1.2](NH3)5 and [Rb([18]crown-6)Rb3][Si7.5Ge1.5](NH3)4

被引：19

作者：

Waibel, Markus ^{[1
]}

Benda, Christian B. ^{[1
]}

Wahl, Bernhard ^{[1
]}

Faessler, Thomas F. ^{[1
]}

机构：

[1] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 46期

关键词：

cluster compounds; germanium; silicon; zintl anions; zintl phases; AMORPHOUS-SILICON; GERMANIUM; IONS; COMPLEXES; ANIONS; GROWTH;

D O I：

10.1002/chem.201101393

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Towards silicon microelectronics: Dissolution of the heteroatomic Group 14 element Zintl phase Rb12Si12Ge5 in liquid ammonia led to the isolation of two [E9]4- clusters with Si and Ge mixed site occupation. The existence of [Si7.5(1)Ge 1.5(1)]4- and [Si7.8(1)Ge1.2(1)] 4- as soluble ions opens new synthetic routes for mixed metal semiconductors (see figure). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12928 / 12931

页数：4

共 27 条

[1] Si94- Anions in Solution - Structures of the Solvates Rb4Si9•4.75NH3 and [Rb(18-crown-6)]Rb3Si9•4NH3, and Chemical Bonding in Si94-
Joseph, Stefanie
Suchentrunk, Christof
Kraus, Florian
Korber, Nikolaus
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (31) : 4641 - 4647
[2] Synthesis and crystal structures of [K(18-crown-6)][Rb(18-crown-6)]2Ge9•6NH3,[Rb(18-crown-6)]3Ge9•9NH3 and [Cs(18-crown-6)]3Ge9•6NH3
Suchentrunk, C
Korber, N
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[3] Synthesis and crystal structures of the polygermanide ammoniates K4Ge9•9NH3, Rb4Ge9•5NH3 and CS6Ge18•4NH3
Suchentrunk, C
Daniels, J
Somer, M
Carrillo-Cabrera, W
Korber, N
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[4] Ge52- Zintl anions:: synthesis and crystal structures of [K([2.2.2]-crypt]2Ge5•4NH3 and [Rb([2.2.2]-crypt]2Ge5•4NH3
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[5] Synthesis and Crystal Structure of M([12]crown-4)2O3 • 1.5 NH3 with M = K, Rb
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[6] [(K,Rb)@([2.2.2]crypt)]2(K,Rb)4[Si9W(CO)4]•13.4 NH3 - The First Tungsten Functionalized Silicon Zintl Cluster
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Westermair, Franz F.
Gschwind, Ruth M.
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ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2023, 649 (19):
[7] Dimers of heptapnictide anions:: As144- and P144- in the crystal structures of [Rb(18-crown-6)]4As14•6NH3 and [Li(NH3)4]4P14•NH3
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Aschenbrenner, Juergen C.
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[8] [A([18]crown-6)]2[Pt(CO)3] . 10 NH3 (A=K, Rb) - A crystal structure containing the long postulated [Pt(CO)3]2-
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[9] Mixed Tetrahedral Zintl Clusters: Single Crystal Structure Determination of [Si4-xGex]4-, [(MesCu)2(Si4-xGex)]4-, and the 29Si MAS NMR Spectra of A4Si2Ge2 (A=K, Rb)
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[10] Ammonolysis reaction of (NH4)(2)GeF6 - Synthesis and structure of NH4[Ge(NH3)F-5]
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Schweda, E
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