(Arene)ruthenium catalysts for olefin metathesis

被引：0

作者：

Bruneau, Christian ^{[1
]}

Fischmeister, Cedric ^{[1
]}

Dixneuf, Pierre H. ^{[1
]}

机构：

[1] Univ Rennes 1, CNRS, UMR6226, Sci Chim Rennes Catalyse & Organometall, Rennes, France

来源：

CHIMICA OGGI-CHEMISTRY TODAY | 2009年 / 27卷 / 03期

关键词：

RING-OPENING METATHESIS; RUTHENIUM ALLENYLIDENE COMPLEXES; HETEROCYCLIC CARBENE PRECURSORS; HIGHLY-ACTIVE CATALYSTS; CLOSING METATHESIS; INDENYLIDENE COMPLEXES; ALKENE METATHESIS; POLYMERIZATION ROMP; IONIC LIQUIDS; IN-SITU;

D O I：

暂无

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

The involvement of (arene) ruthenium complexes in olefin metathesis is reviewed. (RuCl2(p-cymene))(2) is a useful catalyst precursor either in the presence of additives able to generate reactive ruthenium carbene species in situ, or after activation by irradiation. Well-defined (arene) ruthenium allenylidene complexes represent a special class of ionic precursors able to generate active ruthenium indenylidene intermediates upon thermal activation or activation by strong acids.

引用

页码：17 / 19

页数：3

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