Inversion of stereoselectivity in the association between tris(oxalato)cobaltate(III) and bovine serum albumin by the addition of dioxane to aqueous solutions

被引：1

作者：

Taura, T ^{[1
]}

机构：

[1] Univ Aichi Prefecture, Dept Chem, Mizuho Ku, Nagoya, Aichi 467, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 02期

关键词：

oxalato complexes; cobalt complexes; bovine serum albumin; stereoselectivity; circular dichroism; solvent effect;

D O I：

10.1016/S1387-7003(98)00019-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Measuring the Pfeiffer effect of the addition of bovine serum albumin (BSA) as an optically active environment to a tris(oxalato) cobaltate(III) anion, [Co(ox)(3)](3-), we found that the Lambda-enantiomer of the complex anion is enriched in 5 or 10% dioxanewater solutions but the Delta-enantiomer is concentrated in aqueous solution, where the enantiomeric excess is 72% (Lambda rich) in 10% dioxanewater solution. (C) 1998 Elsevier Science S.A.

引用

页码：77 / 79

页数：3

共 16 条

[1] Inversion of stereoselectivity in the association between tris(oxalato) cobaltate(III) and bovine serum albumin by the addition of dioxane to aqueous solutions (vol 1, pg 77, 1998)
Taura, T
INORGANIC CHEMISTRY COMMUNICATIONS, 1999, 2 (01) : 35 - 35
[2] Chiral recognition of tris(oxalato)cobaltate(III) anions by bovine serum albumin
Department of Chemistry, University of Aichi Prefecture, Takadacho 3-28, Mizuho-ku, Nagoya 467, Japan
Inorg. Chim. Acta, 1-2 (1-3):
[3] Chiral recognition of tris(oxalato)cobaltate(III) anions by bovine serum albumin
Taura, T
INORGANICA CHIMICA ACTA, 1996, 252 (1-2) : 1 - 3
[4] MECHANISMS OF TITANIUM(III) REDUCTION OF TRIS(1,10-PHENANTHROLINE)COBALT(III), TRIS(OXALATO)COBALTATE(III), AND TRIS(1,10-PHENANTHROLINE)IRON(III) IN AQUEOUS-SOLUTIONS
AKINYUGHA, N
IGE, J
OJO, JF
OLUBUYIDE, O
SIMOYI, R
INORGANIC CHEMISTRY, 1978, 17 (02) : 218 - 221
[5] Association Constants in the Bovine Serum Albumin/Human Serum Albumin–Tween 20 System in Aqueous Solutions
I. M. Vlasova
A. A. Vlasov
G. R. Grapendaal
A. M. Saletskii
Russian Journal of Physical Chemistry A, 2018, 92 : 714 - 718
[6] KINETICS OF THE REDUCING REACTION OF THE TRIS(OXALATO)COBALTATE(III) ION INDUCED BY THE REACTION BETWEEN COPPER(II) AND THIOSULFATE IN AQUEOUS-SOLUTION
KIMURA, M
ISHIBASHI, M
INORGANICA CHIMICA ACTA, 1987, 129 (01) : 69 - 74
[7] Association Constants in the Bovine Serum Albumin/Human Serum Albumin-Tween 20 System in Aqueous Solutions
Vlasova, I. M.
Vlasov, A. A.
Grapendaal, G. R.
Saletskii, A. M.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 92 (04) : 714 - 718
[8] THE VISCOSITY OF AQUEOUS SOLUTIONS OF BOVINE SERUM ALBUMIN BETWEEN PH 4.3 AND 10.5
TANFORD, C
BUZZELL, JG
JOURNAL OF PHYSICAL CHEMISTRY, 1956, 60 (02): : 225 - 231
[9] Interaction of bovine serum albumin with nonionic surfactant Tween 80 in aqueous solutions: Complexation and association
N. M. Zadymova
G. P. Yampol’skaya
L. Yu. Filatova
Colloid Journal, 2006, 68 : 162 - 172
[10] Interaction of bovine serum albumin with nonionic surfactant Tween 80 in aqueous solutions: Complexation and association
Zadymova, NM
Yampol'skaya, GP
Filatova, LY
COLLOID JOURNAL, 2006, 68 (02) : 162 - 172

← 1 2 →