Ambient synthesis of metal-covalent organic frameworks with Fe-iminopyridine linkages

被引：6
|
作者：
Feng, Tiantian [1 ,2 ,3 ]
Sun, Bing [1 ]
Hao, Qing [2 ,3 ]
Li, Jing [4 ]
Xu, Ying [2 ,3 ]
Shang, Hong [1 ]
Wang, Dong [2 ,3 ]
机构：
[1] China Univ Geosci Beijing, Sch Sci, Beijing 100083, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China
[3] Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[4] Beihang Univ, Sch Chem, Minist Educ, Key Lab Bioinspired Smart Interfacial Sci & Techn, Beijing 100191, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 63期
基金：
中国国家自然科学基金;
关键词：
CHEMISTRY;
D O I：
10.1039/d2cc03148e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Highly crystalline Fe-COFs were constructed from the building blocks carrying pyridyl-aldehyde and triamine moieties in the presence of Fe(OTf)(2) and acetic acid under ambient conditions via a subcomponent assembly strategy. The spectral results prove the coordination of atomically distributed Fe(ii) ions with the nitrogen species of covalently formed iminopyridine linkages.
引用
收藏
页码：8830 / 8833
页数：4
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