Encapsulated Fe3O4 into tubular mesoporous carbon as a superior performance anode material for lithium-ion batteries

被引:27
|
作者
Cao, Zhijie [1 ]
Ma, Xiaobo [1 ]
机构
[1] Ningxia Univ, Sch Phys & Elect Elect Engn, Adv Energy Storage Mat & Devices Lab, Yinchuan 750021, Peoples R China
基金
中国国家自然科学基金;
关键词
Lithium-ion batteries; Composite; Fe3O4; Mesoporous carbon; Capacity; ONE-POT SYNTHESIS; HIGH-CAPACITY; ELECTROCHEMICAL PERFORMANCE; HOLLOW SPHERES; STORAGE; NANOPARTICLES; ELECTRODES; NANOSHEETS; STABILITY; NANOSTRUCTURES;
D O I
10.1016/j.jallcom.2019.152542
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A well-defined composite of Fe3O4 encapsulated into tubular mesoporous carbon is prepared as an anode material for lithium-ion batteries. It turns out that up to 67.7 wt% of Fe3O4 nanoparticles are homogeneously embedded into the mesoporous carbon nanotubes. The Fe3O4@tubular mesoporous carbon composites provide effective accommodation for the volume change, fast transport paths for electrons and ions, as well as good contact for nanoparticles, thus exhibiting superior electrochemical performances. The reversible capacity maintains a high specific capacity of similar to 800 mAh g(-1) after 1000 cycles at 2000 mA g(-1), and the electrode still keeps a reasonable level of similar to 400 mAh g(-1) even going through 16000 cycles at 10000 mA g(-1), which makes Fe3O4@tubular mesoporous carbon composite a valuable anode material for lithium-ion batteries. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页数:7
相关论文
共 50 条
  • [1] Graphene Encapsulated Fe3O4 Nanospindles as a Superior Anode Material for Lithium-Ion Batteries
    Zhang, Junhao
    Wan, Sheng
    Yan, Bo
    Wang, Liangbiao
    Qian, Yitai
    [J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2013, 13 (06) : 4364 - 4369
  • [2] Electrochemical performance of carbon encapsulated hollow Fe3O4 nanoparticles as anode material for lithium-ion batteries
    State Key Laboratory of Chemical Resource Engineering, Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China
    [J]. Gongneng Cailiao, 15 (2027-2030):
  • [3] Carbon Coated Fe3O4 Nanospindles as a Superior Anode Material for Lithium-Ion Batteries
    Zhang, Wei-Ming
    Wu, Xing-Long
    Hu, Jin-Song
    Guo, Yu-Guo
    Wan, Li-Jun
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2008, 18 (24) : 3941 - 3946
  • [4] Foam carbon loading Fe3O4 nanoparticles for superior lithium-ion batteries anode material
    Sun, Kailian
    Zhao, Hongbin
    Yao, Jian
    Zhang, Shouquan
    Xu, Jiaxiang
    [J]. IONICS, 2015, 21 (07) : 1901 - 1908
  • [5] Foam carbon loading Fe3O4 nanoparticles for superior lithium-ion batteries anode material
    Kailian Sun
    Hongbin Zhao
    Jian Yao
    Shouquan Zhang
    Jiaxiang Xu
    [J]. Ionics, 2015, 21 : 1901 - 1908
  • [6] Superior electrochemical performance of mesoporous Fe3O4/CNT nanocomposites as anode material for lithium ion batteries
    Abbas, Syed Mustansar
    Ali, Saqib
    Niaz, Niaz Ahmad
    Ali, Nisar
    Ahmed, Rashid
    Ahmad, Nisar
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 611 : 260 - 266
  • [7] Fe3O4/Fe/Carbon Composite and Its Application as Anode Material for Lithium-Ion Batteries
    Zhao, Xiuyun
    Xia, Dingguo
    Zheng, Kun
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (03) : 1350 - 1356
  • [8] A facile synthesis of a carbon-encapsulated Fe3O4 nanocomposite and its performance as anode in lithium-ion batteries
    Prakash, Raju
    Fanselau, Katharina
    Ren, Shuhua
    Mandal, Tapan Kumar
    Kuebel, Christian
    Hahn, Horst
    Fichtner, Maximilian
    [J]. BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 2013, 4 : 699 - 704
  • [9] Fe3O4/PPy composite nanospheres as anode for lithium-ion batteries with superior cycling performance
    Zhao, Jianfeng
    Zhang, Shichao
    Liu, Wenbo
    Du, Zhijia
    Fang, Hua
    [J]. ELECTROCHIMICA ACTA, 2014, 121 : 428 - 433
  • [10] 3-D mesoporous nano/micro-structured Fe3O4/C as a superior anode material for lithium-ion batteries
    Hao, Quanyi
    Lei, Danni
    Yin, Xiaoming
    Zhang, Ming
    Liu, Shuang
    Li, Qiuhong
    Chen, Libao
    Wang, Taihong
    [J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2011, 15 (11-12) : 2563 - 2569