Novel mixed 1D-2D lanthanide coordination polymers based on p-sulfonatocalix[4]arene and 4,4′-bipyridine-N,N′-dioxide where p-sulfonatocalix[4]arene acts as a guest

被引：10

作者：

Husain, Ahmad ^{[1
]}

Oliver, Clive L. ^{[1
]}

机构：

[1] Univ Cape Town, Dept Chem, Ctr Supramol Chem Res, ZA-7701 Rondebosch, South Africa

来源：

CRYSTENGCOMM | 2015年 / 17卷 / 15期

基金：

新加坡国家研究基金会;

关键词：

SUPRAMOLECULAR POLYMERIZATION; LAYER FRAMEWORK; COMPLEXES; METAL; CONFORMATION; INTERPLAY; LIGAND;

D O I：

10.1039/c5ce00153f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel mixed 1D-2D coordination polymers based on 2D [Ln.4,4'-bpdo)(2)(NO3)(2)(H2O)(2)](n) (+) sheets and 1D[Ln(2)(4,4'-bpdo)(2)(C4AS)(NO3)(H2O)(9)](n) chains (Ln = Sm for 1 and Ln = Nd for 2) sustained by pi center dot center dot center dot pi interactions and lattice water facilitated hydrogen bonds have been established. The chains are arranged such that the p-sulfonatocalix[4]arene anions occupy the cavities of the 2D coordination polymer, and so act as guests rather than as hosts, which is their more usual role.

引用

页码：3023 / 3030

页数：8

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