A phenanthro[9,10-d]imidazole-based highly selective fluorescence and visual sensor for Cu2+ ion

被引:4
|
作者
Hou, Siyu [1 ]
Guo, Yan [1 ]
Miao, Tiezheng [1 ]
Fu, Guorui [1 ]
Li, Wentao [1 ]
Liu, Jiaxiang [1 ]
Wang, Baowen [1 ]
Lu, Xingqiang [1 ]
Liu, Lin [1 ,2 ]
Feng, Weixu [3 ]
机构
[1] Northwest Univ, Sch Chem Engn, Shaanxi Key Lab Degradable Med Mat, Xian 710069, Shaanxi, Peoples R China
[2] Yanan Univ, Sch Chem & Chem Engn, Yanan 716000, Shaanxi, Peoples R China
[3] Northwestern Polytech Univ, Sch Chem & Chem Engn, Xian 710029, Shaanxi, Peoples R China
关键词
Fluorescent chemosensor; Cu2+ ion; Sensing mechanism; Phenanthro[9; 10-d]imidazole-derivative; TURN-ON SENSOR; CHEMOSENSOR; DERIVATIVES; MECHANISM; DIVERSE; CU(II); HG(II); METAL; FE3+;
D O I
10.1016/j.optmat.2021.111834
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Through molecular design of a new phenanthro[9,10-d]imidazole-based compound, the probe 4-VB-PI-DMBA (4-VB-PI-DMBA = N,N-dimethyl-4-(1-(4- vinylbenzyl)-1H-phenanthro[9,10-d]imidazole-2-yl)aniline) strongly emissive at lambda em = 462 nm, is capable of the uniquely fluorescent "turn-off" for Cu2+ ion with a detection limit of 30.2 nM. This result shows that the phenanthro[9,10-d]imidazole-derivative with a twisting structure and without proton-donating groups, renders a selective fluorescence and visual sensor platform to Cu2+ ion.
引用
收藏
页数:7
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