Electrochemical detection of atrazine in wastewater samples by copper oxide (CuO) nanoparticles ionic liquid modified electrode

被引:38
|
作者
Kardas, Faruk [1 ]
Beytur, Murat [2 ]
Akyildirim, Onur [3 ]
Yuksek, Haydar [2 ]
Yola, Mehmet Lutfi [4 ]
Atar, Necip [5 ]
机构
[1] Erzincan Univ, Dept Sci Educ, Fac Educ, Erzincan, Turkey
[2] Kafkas Univ, Fac Sci & Letters, Dept Chem, Kars, Turkey
[3] Kafkas Univ, Dept Chem Engn, Fac Engn & Architecture, Kars, Turkey
[4] Iskenderun Tech Univ, Fac Engn & Nat Sci, Dept Biomed Engn, Antakya, Turkey
[5] Pamukkale Univ, Dept Chem Engn, Fac Engn, Denizli, Turkey
关键词
Atrazine; CuO nanoparticles; Ionic liquid; Square wave voltammetry; CARBON-PASTE ELECTRODE; FOOD SAMPLES; PHASE DETERMINATION; IMPRINTED POLYMER; SENSOR; HERBICIDES; ACID; CHROMATOGRAPHY; EXTRACTION; STRATEGY;
D O I
10.1016/j.molliq.2017.10.085
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the present report, a new voltammetric sensor based on copper oxide nanoparticles involved in 2-(3-acetoxy4-methoxybenzylidenamino)-thiophenol (AMT) ionic liquid (CuO NPs/ILs) was developed for atrazine (ATR) analysis. Firstly, the CuO NPs/ILs modified surface was investigated by using transmission electron microscopy (TEM), X-ray diffraction (XRD), cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and energy dispersive X-ray analysis (EDX). The linearity range and the detection limit (LOD) of the prepared sensor were calculated as 1.0 x 10(-11)-2.0 x 10(-9) and 2.0 x 10(-12) M, respectively. Voltammetric sensor was also applied to wastewater samples with high recovery. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:360 / 363
页数:4
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