Light-Gated Cobalt(I) Hydride Catalysed Alkyne Hydroboration

被引：4
|
作者：
Bergamaschi, Enrico [1 ]
Teskey, Christopher J. [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52074 Aachen, Germany
来源：
TETRAHEDRON LETTERS | 2022年 / 98卷
关键词：
Light-gated catalysis; Cobalt hydride; Hydroboration; Alkynes; BORYLATION;
D O I：
10.1016/j.tetlet.2022.153813
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We report a light-gated, catalytic protocol for hydroboration of terminal alkynes based on a bench-stable cobalt(I) hydride complex which undergoes ligand photodissociation with visible light. The products are obtained in good yields and with excellent E-selectivity. (c) 2022 Elsevier Ltd. All rights reserved.
引用
收藏
页数：3
相关论文
共 50 条
  • [1] Introducing a κ4-diazadiene Co(I) hydride catalyst for alkyne hydroboration
    Ben-Daat, Hagit
    Groy, Thomas
    Trovitch, Ryan
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [2] Engineering of a light-gated potassium channel
    Cosentino, Cristian
    Alberio, Laura
    Gazzarrini, Sabrina
    Aquila, Marco
    Romano, Edoardo
    Cermenati, Solei
    Zuccolini, Paolo
    Petersen, Jan
    Beltrame, Monica
    Van Etten, James L.
    Christie, John M.
    Thiel, Gerhard
    Moroni, Anna
    SCIENCE, 2015, 348 (6235) : 707 - 710
  • [3] Engineering of a Light-Gated Potassium Channel
    Moroni, Anna
    Alberio, Laura
    Romano, Edoardo
    Cermenati, Solei
    Beltrame, Monica
    Thiele, Gerhard
    BIOPHYSICAL JOURNAL, 2016, 110 (03) : 6A - 6A
  • [4] Functional investigation of the light-gated Channelrhodopsin
    Spitz, Julia
    Bamberg, Ernst
    BIOPHYSICAL JOURNAL, 2009, 96 (03) : 671A - 671A
  • [5] A light-gated synthetic ion channel
    Jog, Parag V.
    Gin, Mary S.
    ORGANIC LETTERS, 2008, 10 (17) : 3693 - 3696
  • [6] Engineering light-gated glutamate receptors
    Szobota, Stephanie
    Numano, Rika
    Wyart, Claire
    Gorostiza, Pau
    Volgraf, Matthew
    Fortin, Doris L.
    Del Bene, Filippo
    Scott, Ethan K.
    Kramer, Richard H.
    Trauner, Dirk
    Isacoff, Ehud Y.
    BIOPHYSICAL JOURNAL, 2009, 96 (03) : 489A - 489A
  • [7] Engineering light-gated ion channels
    Banghart, Matthew R.
    Volgraf, Matthew
    Trauner, Dirk
    BIOCHEMISTRY, 2006, 45 (51) : 15129 - 15141
  • [8] Engineering of a light-gated potassium channel
    Alberio, L.
    Cosentino, C.
    Gazzarrini, S.
    Aquila, M.
    Romano, E.
    Cermenati, S.
    Zuccolini, P.
    Petersen, J.
    Beltrame, M.
    van Etten, J. L.
    Christie, J. M.
    Thiel, G.
    Moroni, A.
    EUROPEAN BIOPHYSICS JOURNAL WITH BIOPHYSICS LETTERS, 2015, 44 : S212 - S212
  • [9] Artificial Light-Gated Catalyst Systems
    Stoll, Ragnar S.
    Hecht, Stefan
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (30) : 5054 - 5075
  • [10] Applications of light-gated cobalt catalysis to a [2+2+2] cycloaddition polymerization
    Ravetz, Benjamin
    Ruhl, Kyle
    Rovis, Tomislav
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
12345