A three-phase liquid system based on orthocarboxylic acid salts

被引：1
|
作者：
Shapiro, Yu. M. [1 ]
Nichepurenko, V. I. [1 ]
Kuligina, A. V. [1 ]
机构：
[1] Kuban State Technol Univ, Krasnodar, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2007年 / 81卷 / 05期
关键词：
Organic solvents;
D O I：
10.1134/S0036024407050159
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The composition of the three-phase liquid system based on potassium orthobenzoate in a water dioxane solvent was studied. The phases were found to contain benzoic and orthobenzoic acid salts in various association states. The middle layer was considered. Its composition was indicative of the formation of a potassium complex with oxygen-containing ligands. The structure of this complex was similar to that of the associative crown ether structure.
引用
收藏
页码：739 / 741
页数：3
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